Permeability and diffusivity for water transport through hydrogel membranes

作者: Gavin Hoch , Anuj Chauhan , C.J. Radke

DOI: 10.1016/S0376-7388(02)00546-X

关键词: MembraneChemical engineeringThermal diffusivityDiffusionFick's laws of diffusionChromatographyWater contentRelative humidityWater transportChemistryPermeability (earth sciences)

摘要: Abstract Water transport through soft contact lenses is important to their behavior on the human eye. For first time, we report gradient-driven diffusion rates of water HEMA hydrogel membranes prototypical commercial lenses. evaporated from one surface membrane into known relative humidity air, and weight loss a reservoir at other followed in time. Typical permeabilities are around 1–5 cm/s, increasing with saturated content membrane. Binary Fickian coefficients near 10−7 cm2/s. We also garner binary Stefan–Maxwell based Flory–Rehner theory for polymer solutions. useful because, general, they depend less strongly concentration, can be readily incorporated multicomponent though membranes. Both increase somewhat initial individual lens materials.

参考文章(18)
Paul J. Flory, Principles of polymer chemistry ,(1953)
Edmundo Gomes de Azevedo, J. M. Prausnitz, Ruediger N. Lichtenthaler, Molecular Thermodynamics of Fluid-Phase Equilibria ,(1969)
Ross Taylor, R. Krishna, Multicomponent mass transfer ,(1993)
Jeremy P. Meyers, John Newman, Simulation of the Direct Methanol Fuel Cell II. Modeling and Data Analysis of Transport and Kinetic Phenomena Journal of The Electrochemical Society. ,vol. 149, ,(2002) , 10.1149/1.1473189
A. I. VICTOROV, C. J. RADKE, J. M. PRAUSNITZ, Molecular thermodynamics for swelling of a bicontinuous gel Molecular Physics. ,vol. 100, pp. 2277- 2297 ,(2002) , 10.1080/00268970210132531
Irving Fatt, A predictive model for dehydration of a hydrogel contact lens in the eye Journal of The British Contact Lens Association. ,vol. 12, pp. 15- 31 ,(1989) , 10.1016/S0141-7037(89)80017-5
D. Hariharan, N.A. Peppas, Modelling of water transport and solute release in physiologically sensitive gels Journal of Controlled Release. ,vol. 23, pp. 123- 135 ,(1993) , 10.1016/0168-3659(93)90038-7
I Fatt, Thomas K Goldstick, Dynamics of water transport in swelling membranes Journal of Colloid Science. ,vol. 20, pp. 962- 989 ,(1965) , 10.1016/0095-8522(65)90068-1