Comparison of adsorption behaviour of light alkanes and alkenes on Kureha activated carbon
作者： W. Zhu , J.C. Groen , A. van Miltenburg , F. Kapteijn , J.A. Moulijn
DOI: 10.1016/J.CARBON.2005.01.010
关键词: Adsorption 、 Physical chemistry 、 Propane 、 Alkene 、 Chemistry 、 Inorganic chemistry 、 Propene 、 Saturation (chemistry) 、 Selectivity 、 Alkane 、 Activated carbon
摘要: Adsorption equilibria of light alkanes and alkenes on Kureha activated carbon were investigated using a volumetric method. Single-component adsorption isotherms are reported at pressures up to 120 kPa temperatures in the range from 194 338 K for ethane ethene 273 358 propane propene. The Toth model appropriately describes equilibrium data over whole conditions. saturation capacity alkene extracted by is higher than corresponding alkane, attributed packing efficiency molecules inside micropores. An interesting reversal alkane/alkene selectivity with pressure observed: low towards driven energetic effects while high due entropic effects.
elsevier.com
sci-hub.se 参考文章(19)
Alan L. Myers, Diego P. Valenzuela, Adsorption equilibrium data handbook ,(1989)
Donald W Breck, Zeolite Molecular Sieves: Structure, Chemistry, and Use ,(1974)
T. J. H. Vlugt, W. Zhu, F. Kapteijn, J. A. Moulijn, B. Smit, R. Krishna, Adsorption of Linear and Branched Alkanes in the Zeolite Silicalite-1 Journal of the American Chemical Society. ,vol. 120, pp. 5599- 5600 ,(1998) , 10.1021/JA974336T
W. Zhu, F. Kapteijn, J. A. Moulijn, M. C. den Exter, J. C. Jansen, Shape Selectivity in Adsorption on the All-Silica DD3R Langmuir. ,vol. 16, pp. 3322- 3329 ,(2000) , 10.1021/LA9914007
Weidong Zhu, Johan C. Groen, Freek Kapteijn, Jacob A. Moulijn, Adsorption of Butane Isomers and SF6 on Kureha Activated Carbon: 1. Equilibrium Langmuir. ,vol. 20, pp. 5277- 5284 ,(2004) , 10.1021/LA030264+
S Mohanty, A.V McCormick, Prospects for principles of size and shape selective separations using zeolites Chemical Engineering Journal. ,vol. 74, pp. 1- 14 ,(1999) , 10.1016/S1385-8947(99)00059-5
Pierre Pascual, Philippe Ungerer, Bernard Tavitian, Anne Boutin, Development of a transferable guest-host force field for adsorption of hydrocarbons in zeolites. II. Prediction of alkenes adsorption and alkane/alkene selectivity in silicalite Journal of Physical Chemistry B. ,vol. 108, pp. 393- 398 ,(2004) , 10.1021/JP0358634
R. Krishna, B. Smit, T. J. H. Vlugt, Sorption-Induced Diffusion-Selective Separation of Hydrocarbon Isomers Using Silicalite Journal of Physical Chemistry A. ,vol. 102, pp. 7727- 7730 ,(1998) , 10.1021/JP982438F
W. Zhu, F. Kapteijn, J. A. Moulijn, Adsorption of light alkanes on silicalite-1: Reconciliation of experimental data and molecular simulations Physical Chemistry Chemical Physics. ,vol. 2, pp. 1989- 1995 ,(2000) , 10.1039/B000444H
T. J. H. Vlugt, R. Krishna, B. Smit, Molecular Simulations of Adsorption Isotherms for Linear and Branched Alkanes and Their Mixtures in Silicalite Journal of Physical Chemistry B. ,vol. 103, pp. 1102- 1118 ,(1999) , 10.1021/JP982736C