Studies on the Mechanism and Kinetics of Propylene Oligomerization and Hydrooligomerization on Zeolites
作者： Shawky M. Hassan , G. M. Panchenkov , O. I. Kuznetsov
DOI: 10.1246/BCSJ.50.2597
关键词: Metal ions in aqueous solution 、 Chemistry 、 Cyclobutane 、 Zeolite 、 Derivative (chemistry) 、 Kinetics 、 Photochemistry
摘要: The propylene conversion process has been studied in the presence of synthetic zeolites different types and metal ions. NiX zeolite is selective for oligomerization propylene. On other ions, hydro-oligomerization took place. It found that obtained 3-methylpentenes are primary products oligomerization. A scheme mechanism proposed assuming an intermediate a cyclobutane derivative. explains formation all on zeolites.
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