Static heterogeneities in liquid water
作者： H.Eugene Stanley , Sergey V. Buldyrev , Nicolas Giovambattista
DOI: 10.1016/J.PHYSA.2004.06.045
关键词: Physical chemistry 、 Chemical physics 、 Local structure 、 Liquid water 、 Amorphous solid 、 Hydrogen bond 、 Phase (matter) 、 Molecule 、 Metastability 、 Tetrahedron 、 Materials science
摘要: Abstract The thermodynamic behavior of water seems to be closely related static heterogeneities. These heterogeneities are the local structure molecules, and when properly characterized, may offer an economical explanation data. key feature liquid is not so much that existence hydrogen bonds, first pointed out by Linus Pauling, but rather geometry molecules spherical or oblong tetrahedral. In consideration heterogeneities, this critical. Recent experiments suggested more than one phase amorphous solid water, while simulations suggest these phases metastable with respect another, in fact there only two stable phases.
harvard.edu
core.ac.uk
elsevier.com
sci-hub.se 参考文章(35)
Yoshinori Katayama, Takeshi Mizutani, Wataru Utsumi, Osamu Shimomura, Masaaki Yamakata, Ken-ichi Funakoshi, A first-order liquid–liquid phase transition in phosphorus Nature. ,vol. 403, pp. 170- 173 ,(2000) , 10.1038/35003143
Osamu Mishima, H. Eugene Stanley, Decompression-induced melting of ice IV and the liquid–liquid transition in water Nature. ,vol. 392, pp. 164- 168 ,(1998) , 10.1038/32386
Jeffrey R. Errington, Pablo G. Debenedetti, Relationship between structural order and the anomalies of liquid water Nature. ,vol. 409, pp. 318- 321 ,(2001) , 10.1038/35053024
New Kinds of Phase Transitions: Transformations in disordered Substances Physics of Particles and Nuclei. ,vol. 36, ,(2002) , 10.1007/978-94-010-0595-1
Giancarlo Franzese, Gianpietro Malescio, Anna Skibinsky, Sergey V. Buldyrev, H. Eugene Stanley, Generic mechanism for generating a liquid–liquid phase transition Nature. ,vol. 409, pp. 692- 695 ,(2001) , 10.1038/35055514
Peter H. Poole, Francesco Sciortino, Ulrich Essmann, H. Eugene Stanley, Phase behaviour of metastable water Nature. ,vol. 360, pp. 324- 328 ,(1992) , 10.1038/360324A0
Giancarlo Franzese, H. Eugene Stanley, A theory for discriminating the mechanism responsible for the water density anomaly Physica A-statistical Mechanics and Its Applications. ,vol. 314, pp. 508- 513 ,(2002) , 10.1016/S0378-4371(02)01186-X
Osamu Mishima, Reversible first‐order transition between two H2O amorphs at ∼0.2 GPa and ∼135 K Journal of Chemical Physics. ,vol. 100, pp. 5910- 5912 ,(1994) , 10.1063/1.467103
S. Engemann, H. Reichert, H. Dosch, J. Bilgram, V. Honkimäki, A. Snigirev, Interfacial melting of ice in contact with SiO(2). Physical Review Letters. ,vol. 92, pp. 205701- 205701 ,(2004) , 10.1103/PHYSREVLETT.92.205701
Peter H. Poole, Mahin Hemmati, C. Austen Angell, Comparison of thermodynamic properties of simulated liquid silica and water Physical Review Letters. ,vol. 79, pp. 2281- 2284 ,(1997) , 10.1103/PHYSREVLETT.79.2281