Asymmetric photoredox transition-metal catalysis activated by visible light
作者： Haohua Huo , Xiaodong Shen , Chuanyong Wang , Lilu Zhang , Philipp Röse
DOI: 10.1038/NATURE13892
关键词: Chirality (chemistry) 、 Radical ion 、 Chemistry 、 Enantioselective synthesis 、 Catalysis 、 Photochemistry 、 Radical 、 Organocatalysis 、 Photoredox catalysis 、 Asymmetric induction
摘要: … of the α-alkylation products are consistent with this mechanistic picture. This … catalysis cycle but also constitutes the in situ generated active visible-light photosensitizer. The reaction …
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sci-hub.se 参考文章(32)
David A. Nagib, Mark E. Scott, David W. C. MacMillan, Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis Journal of the American Chemical Society. ,vol. 131, pp. 10875- 10877 ,(2009) , 10.1021/JA9053338
Robert Howard Grubbs, Daniel J. O'Leary, Applications in organic synthesis Wiley-VCH. ,(2015)
Dennis P Curran, Ned A Porter, Bernd Giese, Stereochemistry of Radical Reactions: Concepts, Guidelines, and Synthetic Applications ,(1996)
Giulia Bergonzini, Corinna S. Schindler, Carl-Johan Wallentin, Eric N. Jacobsen, Corey R. J. Stephenson, Photoredox activation and anion binding catalysis in the dual catalytic enantioselective synthesis of β-amino esters Chemical Science. ,vol. 5, pp. 112- 116 ,(2014) , 10.1039/C3SC52265B
D. M. Schultz, T. P. Yoon, Solar Synthesis: Prospects in Visible Light Photocatalysis Science. ,vol. 343, pp. 1239176- 1239176 ,(2014) , 10.1126/SCIENCE.1239176
Hui-Wen Shih, Mark N. Vander Wal, Rebecca L. Grange, David W. C. MacMillan, Enantioselective α-benzylation of aldehydes via photoredox organocatalysis. Journal of the American Chemical Society. ,vol. 132, pp. 13600- 13603 ,(2010) , 10.1021/JA106593M
Christopher K. Prier, Danica A. Rankic, David W. C. MacMillan, Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis Chemical Reviews. ,vol. 113, pp. 5322- 5363 ,(2013) , 10.1021/CR300503R
R. Brimioulle, T. Bach, Enantioselective Lewis acid catalysis of intramolecular enone [2+2] photocycloaddition reactions. Science. ,vol. 342, pp. 840- 843 ,(2013) , 10.1126/SCIENCE.1244809
Andreas Bauer, Felix Westkämper, Stefan Grimme, Thorsten Bach, Catalytic enantioselective reactions driven by photoinduced electron transfer Nature. ,vol. 436, pp. 1139- 1140 ,(2005) , 10.1038/NATURE03955
H SATO, A YAMAGISHI, Application of the ΔΛ isomerism of octahedral metal complexes as a chiral source in photochemistry Journal of Photochemistry and Photobiology C-photochemistry Reviews. ,vol. 8, pp. 67- 84 ,(2007) , 10.1016/J.JPHOTOCHEMREV.2007.04.001