Bidentate ligands formed by self-assembly.
作者： Vincent F. Slagt , Piet W. N. M. van Leeuwen , Joost N. H. Reek
DOI: 10.1039/B306683E
关键词: Polymer chemistry 、 Chemistry 、 Stereochemistry 、 Supramolecular chemistry 、 Hydroformylation 、 Chelation 、 Rhodium 、 Monomer 、 Porphyrin 、 Denticity 、 Zinc
摘要: A novel supramolecular strategy to prepare bidentate ligands via the assembly of functionalised monomeric on a dimeric zinc(II) porphyrin template is presented; assembled show chelating behaviour and their rhodium complexes display enhanced selectivity in hydroformylation compared non-template analogue.
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