Efficient generation of thionitrosoranes (ArNS) by fragmentation of N-(arylaminothio)phthalimides
作者： Martin R. Bryce , Paul C. Taylor
DOI: 10.1039/C39880000950
关键词: Chemical decomposition 、 Adduct 、 Ene reaction 、 Sulfenamide 、 Fragmentation (mass spectrometry) 、 Chemistry 、 Phthalimides 、 Photochemistry 、 Imide
摘要: Base-induced fragmentation of a series N-(arylaminothio)phthalimides (3) provides an efficient route to transient thionitrosoranes (2); compounds (2) have been trapped as Diels–Alder cycloadducts with butadiene and 2,3-dimethylbutadiene, or ene adducts alkenes.
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