Thorium[IV], Uranium[VI] and Ce[III] complexes with bidentate and tridentate Schiff bases

作者: Mohamed R. Mahmoud , Issa M. Issa , Mahmoud S. El-Melliegy , S. A. El-Gyar

DOI: 10.1007/BF00907307

关键词: Schiff baseInfrared spectroscopyCeriumUraniumStability constants of complexesNuclear chemistryInorganic chemistryDenticityTitrationThoriumChemistry

摘要: Thorium(IV), Uranium(VI) and Cerium(III) complexes with some bidentate tridentateSchiff bases-derived from salicyladehyde-have been prepared. The effect of the molecular structure theSchiff base molecule on its tendency towards complex formation has studied. structures have investigated by elemental analysis, molar ratio continuous variation spectrophotometric methods, infrared spectra conductometric titrations; apparent constants determined as well.

参考文章(11)
F. Fairbrother, A text-book of quantitative inorganic analysis Journal of Inorganic and Nuclear Chemistry. ,vol. 25, pp. 745- ,(1963) , 10.1016/0022-1902(63)80176-1
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
P. Teyssie, J.J. Charette, Physico-chemical properties of co-ordinating compounds—III: Infra-red spectra of N-salicyclidenealkylamines and their chelates Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 19, pp. 1407- 1423 ,(1963) , 10.1016/0371-1951(63)80003-X
M.D. Hobday, T.D. Smith, N,N'-ethylenebis(salicylideneiminato) transition metal ion chelates Coordination Chemistry Reviews. ,vol. 9, pp. 311- 337 ,(1973) , 10.1016/S0010-8545(00)82081-0
Sailendra Nath Poddar, Complex Compounds of Schiff's bases of 3‐aldehydo‐salicylic acid Zeitschrift für anorganische und allgemeine Chemie. ,vol. 322, pp. 326- 336 ,(1963) , 10.1002/ZAAC.19633220512
J.E. Kovacic, The CN stretching frequency in the infrared spectra of Schiff's base complexes—I. Copper complexes of salicylidene anilines Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 23, pp. 183- 187 ,(1967) , 10.1016/0584-8539(67)80219-8
Shoichiro Yamada, Akira Takeuchi, Dioxouraniun(VI) Complexes of Schiff Bases Obtained from Substituted Salicylaldehydes and Alkyl Amines Bulletin of the Chemical Society of Japan. ,vol. 42, pp. 2549- 2551 ,(1969) , 10.1246/BCSJ.42.2549
Keihei Ueno, Arthur E. Martell, Infrared Studies on Synthetic Oxygen Carriers. The Journal of Physical Chemistry. ,vol. 60, pp. 1270- 1275 ,(1956) , 10.1021/J150543A029
Harold H. Freedman, Intramolecular H-Bonds. I. A Spectroscopic Study of the Hydrogen Bond between Hydroxyl and Nitrogen Journal of the American Chemical Society. ,vol. 83, pp. 2900- 2905 ,(1961) , 10.1021/JA01474A026