Advances in the Chemistry of Stable Hydrocarbon Radicals

作者: V D Sholle , Eduard G Rozantsev

DOI: 10.1070/RC1973V042N12ABEH002781

关键词: ChemistryHydrocarbonComputational chemistryCarbonRadicalOrganic chemistry

摘要: The current data on the structure of tervalent carbon radicals are examined and their principal spectroscopic characteristics presented. latest studies synthesis stable hydrocarbon radicals, including ultrastable perchlorotriarylmethyl considered together with classical investigations. In discussion chemical properties, much attention has been devoted to dimerisation triarylmethyls, since this problem altered drastically traditional concept radicals. Modern ideas concerning certain biradicals bibliography includes 150 referepces.

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