Ein einfaches Verfahren zur Herstellung von organozinnaziden. Synthese and struktur der sterisch gehinderten Stannylazide tBu3 SnN3 und tBu2 Sn(N3)2
作者： Dieter Hänssgen , Martin Jansen , Christiane Leben , Thomas Oster
DOI: 10.1016/0022-328X(95)05420-T
关键词: Steric effects 、 Chemistry 、 Stereochemistry 、 Group (periodic table) 、 Molecule
摘要: Abstract Sterically crowded stannyl azides t Bu n Sn(N 3 ) 4- ( IIa,b have been prepared for the first time by reactions of stannylamines Sn(NHR) Ia,b with Me SiN a : = 3, R H; b 2, Bu). The novel compounds were characterized NMR 1 H, 13 C) and mass spectroscopy their molecular structure determined X-ray crystallography IIa space group P 2 / m , Z =2; IIb 4).
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sci-hub.se 参考文章(20)
Torazô Hitomi, Sinpei Kozima, Formation of organotin-nitrogen bonds Journal of Organometallic Chemistry. ,vol. 127, pp. 273- 280 ,(1977) , 10.1016/S0022-328X(00)89717-X
John Christian Bailar, Harry Julius Emeléus, Sir Ronald Nyholm, A. F. Trotman-Dickenson, Comprehensive inorganic chemistry Pergamon Press , Compendium (Exclusive distributors in the Western Hemisphere). ,(1973)
E. O. Schlemper, Doyle Britton, The Crystal Structure of Trimethyltin Cyanide Inorganic Chemistry. ,vol. 5, pp. 507- 510 ,(1966) , 10.1021/IC50038A002
N. Bertazzi, G. Alonzo, R. Barbieri, R.H. Herber, Studies on bis(trimethyltin) azide hydroxide and hexamethyl-1,5-diazidotristannoxane by Mössbauer and vibrational spectroscopy Journal of Organometallic Chemistry. ,vol. 65, pp. 23- 31 ,(1974) , 10.1016/S0022-328X(00)83883-8
Rudolf Allmann, Rüdiger Hohlfeld, Alicja Waskowska, Jörg Lorberth, Die molekül- und kristallstruktur von trimethylzinnazid Me3SnN3 Journal of Organometallic Chemistry. ,vol. 192, pp. 353- 358 ,(1980) , 10.1016/S0022-328X(00)81226-7
Herbert W. Roesky, Hartmut Wiezer, Substitutionsreaktionen an zinn- und siliciumhaltigen Verbindungen Chemische Berichte. ,vol. 107, pp. 3186- 3190 ,(1974) , 10.1002/CBER.19741071005
D. Hänssgen, H. Puff, N. Beckermann, Synthese der ersten mono-t-butylzinnelementverbindungen Journal of Organometallic Chemistry. ,vol. 293, pp. 191- 195 ,(1985) , 10.1016/0022-328X(85)80287-4
Heinrich Puff, Dieter Hänssgen, Norbert Beckermann, Albrecht Roloff, Willi Schuh, Zur struktur einiger cyclischer Diorganylzinn—Stickstoff-Verbindungen Journal of Organometallic Chemistry. ,vol. 373, pp. 37- 47 ,(1989) , 10.1016/0022-328X(89)85022-3
Dieter Hänssgen, Martin Jansen, Wilfried Assenmacher, Heinz Salz, Zur struktur sterisch gehinderter Zinn-Elementverbindungen: Kristallstruktur der Zinn-Schwefel-Stickstoff-Ringe [(tBu2Sn)2N2S2] und [(tBu2Sn)N2S2]2 Journal of Organometallic Chemistry. ,vol. 445, pp. 61- 64 ,(1993) , 10.1016/0022-328X(93)80187-G
Dieter Hänssgen, Armin Dörr, Heribert Hens, Roland Jeske, Reaktionen mit primären Stannylphosphinen: Synthese offenkettiger und ring-oligomerer Zinn-Phosphorverbindungen Journal of Organometallic Chemistry. ,vol. 487, pp. 17- 21 ,(1995) , 10.1016/0022-328X(94)05091-O