Coupled chemo-electro-mechanical finite element simulation of hydrogels: II. Electrical stimulation

作者: Dirk Ballhause , Thomas Wallmersperger

DOI: 10.1088/0964-1726/17/4/045011

关键词: Self-healing hydrogelsElectric potentialArtificial muscleMaterials scienceSwellingViscoelasticityComposite materialPhase (matter)Work (thermodynamics)Polyelectrolyte

摘要: Certain polyelectrolyte gels are distinguished by a large swelling or bending capability under the influence of external physical, chemical electrical stimuli. In this paper we investigate mechanisms occurring in due to externally applied electric fields. By applying coupled chemo-electro-mechanical model which is extended and predestined for stimulation, describe concentrations potential both gel solution as well locally different shrinking gel. The local change geometry formulated osmotic pressure difference between next phase. addition effect, domain leads variation concentration bound groups thus mobile ions. As focus presented work demonstrate superiority fully description compared previously developed one-way chemo-electric mechanical model. Finally, qualitative comparison with experimental results, validity stimulation demonstrated.

参考文章(47)
Wolfgang Ehlers, Foundations of multiphasic and porous materials Porous Media. pp. 3- 86 ,(2002) , 10.1007/978-3-662-04999-0_1
J. Ricka, Toyoichi Tanaka, Swelling of Ionic Gels : Quantitative Performance of the Donnan Theory Macromolecules. ,vol. 17, pp. 2916- 2921 ,(1984) , 10.1021/MA00142A081
Hua Li, Rongmo Luo, K.Y. Lam, Modeling of ionic transport in electric-stimulus-responsive hydrogels Journal of Membrane Science. ,vol. 289, pp. 284- 296 ,(2007) , 10.1016/J.MEMSCI.2006.12.011
W. M. Lai, J. S. Hou, V. C. Mow, A triphasic theory for the swelling and deformation behaviors of articular cartilage. Journal of Biomechanical Engineering-transactions of The Asme. ,vol. 113, pp. 245- 258 ,(1991) , 10.1115/1.2894880
Paul J. Flory, John Rehner, Statistical Mechanics of Cross‐Linked Polymer Networks I. Rubberlike Elasticity The Journal of Chemical Physics. ,vol. 11, pp. 512- 520 ,(1943) , 10.1063/1.1723791
Tohru Shiga, Yoshiharu Hirose, Akane Okada, Toshio Kurauchi, Electrically Driven Polymer Gel Finger Working in the Air Journal of Intelligent Material Systems and Structures. ,vol. 4, pp. 553- 557 ,(1993) , 10.1177/1045389X9300400417
Paul J. Flory, John Rehner, Statistical Mechanics of Cross‐Linked Polymer Networks II. Swelling The Journal of Chemical Physics. ,vol. 11, pp. 521- 526 ,(1943) , 10.1063/1.1723792
J.M. Huyghe, J.D. Janssen, Quadriphasic mechanics of swelling incompressible porous media International Journal of Engineering Science. ,vol. 35, pp. 793- 802 ,(1997) , 10.1016/S0020-7225(96)00119-X
Yong Li, Toyoichi Tanaka, Kinetics of swelling and shrinking of gels Journal of Chemical Physics. ,vol. 92, pp. 1365- 1371 ,(1990) , 10.1063/1.458148
Satoshi Tadokoro, Shinji Yamagami, Toshi Takamori, Keisuke Oguro, Modeling of Nafion-Pt composite actuators (ICPF) by ionic motion Smart Structures and Materials 2000: Electroactive Polymer Actuators and Devices (EAPAD). ,vol. 3987, pp. 92- 102 ,(2000) , 10.1117/12.387767