Changes in chemical quality indices during long-term storage of palm-olein oil under heated storage and transport-type conditions

作者: Gretel H van der Merwe , Lourens M du Plessis , John RN Taylor

DOI: 10.1002/JSFA.1609

关键词: WarehouseVegetable oilBiochemistryTocopherolCopperFood preservationFood scienceElaeis guineensisChemistryHexanalPeroxide value

摘要: Six quality indices, namely free fatty acids (FFA), peroxide value (PV), anisidine (AV), oxidative stability index (OSI), total tocopherols and headspace volatiles (hexanal, t-2-hexenal t,t-2,4-decadienal), were evaluated in a long-term storage trial of 52weeks at 50 ◦ Co f palm-olein, monounsaturated oil. Three concentrations copper (0.035, 0.17 0.69mgkg −1 ) added. FFA values for all the sample treatments increased slightly over period but remained within acceptable limits. PV copper-containing samples declined initially then stable up to week 40, after which it 0.035 0.17mgkg samples. However, control (no added copper) steadily above limit. AV much more than that control. OSI tocopherol copper- containing markedly lower those t-2-Hexenal did not increase during period, whereas hexanal slower rate Conversely, had high levels t,t-2,4-decadienal none. AV, are most valuable indices assessing oil quality, FFA, can be misleading.  2003 Society Chemical Industry

参考文章(21)
Cong Chiew Let, A. Gapor Mohd Top, Effects of moisture and trace metals on oil quality. Proceedings of workshop on quality in the palm oil industry.. pp. 46- 66 ,(1985)
Kristina Andersson, Hans Lingnert, Influence of oxygen and copper concentration on lipid oxidation in rapeseed oil Journal of the American Oil Chemists' Society. ,vol. 75, pp. 1041- 1046 ,(1998) , 10.1007/S11746-998-0284-4
M. T. Morales, J. J. Rios, R. Aparicio, Changes in the Volatile Composition of Virgin Olive Oil during Oxidation:  Flavors and Off-Flavors Journal of Agricultural and Food Chemistry. ,vol. 45, pp. 2666- 2673 ,(1997) , 10.1021/JF960585+
A.-M. Lampi, V. Piironen, A. Hopia, P. Koivistoinen, Characterization of the Oxidation of Rapeseed and Butter Oil Triacylglycerols by Four Analytical Methods LWT - Food Science and Technology. ,vol. 30, pp. 807- 813 ,(1997) , 10.1006/FSTL.1997.0273
J.C. Miller, P.J. Worsfold, J.N. Miller, Statistics for Analytical Chemistry ,(1993)
K. Warner, E. N. Frankel, Flavor stability of soybean oil based on induction periods for the formation of volatile compounds by gas chromatography Journal of the American Oil Chemists' Society. ,vol. 62, pp. 100- 103 ,(1985) , 10.1007/BF02541502
B. Benjellourr, T. Talou, M. Delmas, A. Gaset, Oxidation of rapeseed oil: Effect of metal traces Journal of the American Oil Chemists’ Society. ,vol. 68, pp. 210- 211 ,(1991) , 10.1007/BF02657772