Microwave Spectra of Molecules Exhibiting Internal Rotation. V. Barrier Height in Ethyl Chloride and Ethyl Bromide
作者： David R. Lide
DOI: 10.1063/1.1729937
关键词: Excited state 、 Ethyl Chloride 、 Bromide 、 Molecule 、 Quadrupole 、 Chemistry 、 Computational chemistry 、 Microwave 、 Hyperfine structure 、 Analytical chemistry 、 Internal rotation 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: The barriers to internal rotation in C2H5Cl and C2H5Br have been determined from the splittings of microwave lines first excited torsional state. values obtained are V0=3560±12 cal/mole for V0=3567±30 C2H5Br. influence nuclear quadrupole hyperfine structure on is discussed.
scitation.org
harvard.edu
aip.org 
sci-hub.se 参考文章(7)
Lester W. Daasch, C. Y. Liang, J. Rud Nielsen, Vibrational Spectra and Calculated Thermodynamic Properties of Ethyl Chloride and 1,1‐Dichloroethane The Journal of Chemical Physics. ,vol. 22, pp. 1293- 1303 ,(1954) , 10.1063/1.1740386
David R. Lide, Structure of the Methylamine Molecule. I. Microwave Spectrum of CD3ND2 The Journal of Chemical Physics. ,vol. 27, pp. 343- 352 ,(1957) , 10.1063/1.1743727
Dudley R. Herschbach, Internal Barrier in CH3CH2F and CH3CHF2 from Torsional Satellites The Journal of Chemical Physics. ,vol. 25, pp. 358- 359 ,(1956) , 10.1063/1.1742888
Kenneth S. Pitzer, Potential energies for rotation about single bonds Discussions of The Faraday Society. ,vol. 10, pp. 66- 73 ,(1951) , 10.1039/DF9511000066
David R. Lide, D. E. Mann, Microwave Spectra of Molecules Exhibiting Internal Rotation. I. Propylene The Journal of Chemical Physics. ,vol. 27, pp. 868- 873 ,(1957) , 10.1063/1.1743867
Roselin S. Wagner, B. P. Dailey, N. Solimene, Microwave Spectrum of Ethyl Bromide The Journal of Chemical Physics. ,vol. 26, pp. 1593- 1596 ,(1957) , 10.1063/1.1743589
Roselin S. Wagner, B. P. Dailey, Microwave Spectrum of Ethyl Chloride The Journal of Chemical Physics. ,vol. 26, pp. 1588- 1593 ,(1957) , 10.1063/1.1743588