Charge-density-wave phase transition in1T−TiSe2:  Excitonic insulator versus band-type Jahn-Teller mechanism

作者: K. Rossnagel , L. Kipp , M. Skibowski

DOI: 10.1103/PHYSREVB.65.235101

关键词: Inverse photoemission spectroscopyAtomic physicsPhotoemission spectroscopySynchrotron radiationCondensed matter physicsCharge density wavePhase transitionAngle-resolved photoemission spectroscopyJahn–Teller effectElectronic structurePhysics

摘要: The influence of the charge-density-wave phase transition on electronic structure $1T\ensuremath{-}{\mathrm{TiSe}}_{2}$ is studied by means high-resolution angle-resolved photoemission spectroscopy with synchrotron radiation. We find that both Se $4p$-type valence band maximum at $\ensuremath{\Gamma}$ and Ti $3d$-type conduction minimum L are lowered upon cooling. Our results explain observed anomalies in transport data appear to be consistent band-type Jahn-Teller mechanism rather than excitonic electron-hole interaction.

参考文章(26)
F. J. Di Salvo, D. E. Moncton, J. V. Waszczak, Electronic properties and superlattice formation in the semimetal TiSe 2 Physical Review B. ,vol. 14, pp. 4321- 4328 ,(1976) , 10.1103/PHYSREVB.14.4321
K. C. Woo, F. C. Brown, W. L. McMillan, R. J. Miller, M. J. Schaffman, M. P. Sears, Superlattice formation in titanium diselenide Physical Review B. ,vol. 14, pp. 3242- 3247 ,(1976) , 10.1103/PHYSREVB.14.3242
M. M. Traum, G. Margaritondo, N. V. Smith, J. E. Rowe, F. J. Di Salvo, TiSe2: Semiconductor, semimetal, or excitonic insulator Physical Review B. ,vol. 17, pp. 1836- 1838 ,(1978) , 10.1103/PHYSREVB.17.1836
O. Anderson, G. Karschnick, R. Manzke, M. Skibowski, The phase transition in the electronic structure of 1T-TiSe2 Solid State Communications. ,vol. 53, pp. 339- 342 ,(1985) , 10.1016/0038-1098(85)90981-0
N. G. Stoffel, S. D. Kevan, N. V. Smith, Experimental band structure of 1T-TiSe2 in the normal and charge-density-wave phases. Physical Review B. ,vol. 31, pp. 8049- 8055 ,(1985) , 10.1103/PHYSREVB.31.8049
O. Anderson, R. Manzke, M. Skibowski, Three-dimensional and relativistic effects in layered 1T-TiSe2. Physical Review Letters. ,vol. 55, pp. 2188- 2191 ,(1985) , 10.1103/PHYSREVLETT.55.2188
Th. Pillo, J. Hayoz, H. Berger, F. Lévy, L. Schlapbach, P. Aebi, Photoemission of bands above the Fermi level: The excitonic insulator phase transition in 1 T − TiSe 2 Physical Review B. ,vol. 61, pp. 16213- 16222 ,(2000) , 10.1103/PHYSREVB.61.16213
Alex Zunger, A. J. Freeman, Band structure and lattice instability of TiSe2 Physical Review B. ,vol. 17, pp. 1839- 1842 ,(1978) , 10.1103/PHYSREVB.17.1839
G A Benesh, A M Woolley, C Umrigar, The pressure dependences of TiS2 and TiSe2 band structures Journal of Physics C: Solid State Physics. ,vol. 18, pp. 1595- 1603 ,(1985) , 10.1088/0022-3719/18/8/007
C. M. Fang, R. A. de Groot, C. Haas, Bulk and surface electronic structure of 1T-TiS2 and 1T-TiSe2 Physical Review B. ,vol. 56, pp. 4455- 4463 ,(1997) , 10.1103/PHYSREVB.56.4455