Internal energy distributions acquired through collisional activation at low and high energies

作者: Hilkka I. Kenttämaa , R.Graham Cooks

DOI: 10.1016/0168-1176(85)85038-2

关键词: Excited stateIonInternal energyAtomic physicsChemistryMass spectrumArgonDissociation (chemistry)Binding energyFragmentation (mass spectrometry)

摘要: … The data show high energy tails in the EI and high energy CID … maximum energy transferred under single collision conditions at low collision energy is small but shifts to higher energies …

参考文章(24)
J. D. Ciupek, D. Zakett, R. G. Cooks, K. V. Wood, High and low energy collision mass spectrometry/mass spectrometry of aza and amino polynuclear aromatic compounds in coal-derived liquids Analytical Chemistry. ,vol. 54, pp. 2215- 2219 ,(1982) , 10.1021/AC00250A019
Ian Howe, Dudley Howard Williams, Calculation and qualitative prediction of mass spectra. Mono- and para-disubstituted benzenes Journal of the American Chemical Society. ,vol. 91, pp. 7137- 7144 ,(1969) , 10.1021/JA01053A041
R. Graham Cooks, Ian Howe, Dudley H. Williams, Structure and fragmentation mechanisms of organic ions in the mass spectrometer Journal of Mass Spectrometry. ,vol. 2, pp. 137- 156 ,(1969) , 10.1002/OMS.1210020202
Sunita Verma, James D. Ciupek, R.Graham Cooks, Isomeric structure distinction using energy and angular resolution: C3H6O+· International Journal of Mass Spectrometry and Ion Processes. ,vol. 62, pp. 219- 225 ,(1984) , 10.1016/0168-1176(84)85197-6
Donald A. Bafus, Emilio J. Gallegos, Robert W. Kiser, An Electron Impact Investigation of Some Alkyl Phosphate Esters The Journal of Physical Chemistry. ,vol. 70, pp. 2614- 2619 ,(1966) , 10.1021/J100880A029
William A. Chupka, Effect of Unimolecular Decay Kinetics on the Interpretation of Appearance Potentials The Journal of Chemical Physics. ,vol. 30, pp. 191- 211 ,(1959) , 10.1063/1.1729875
F. W. McLafferty, P. F. Bente, Richard. Kornfeld, Shih-Chuan. Tsai, Ian. Howe, Metastable ion characteristics. XXII. Collisional activation spectra of organic ions Journal of the American Chemical Society. ,vol. 95, pp. 2120- 2129 ,(1973) , 10.1021/JA00788A007
Willi A. Brand, K. Levsen, Approximate determination of absolute unimolecular rate constants using the field ionization kinetic method International Journal of Mass Spectrometry and Ion Physics. ,vol. 51, pp. 135- 154 ,(1983) , 10.1016/0020-7381(83)85002-5
Philip. Irving, Fred W. McLafferty, Timothy. Wachs, Chava. Lifshitz, Giuseppe. Innorta, Substituent effects in unimolecular ion decompositions. XV. Mechanistic interpretations and the quasi-equilibrium theory Journal of the American Chemical Society. ,vol. 92, pp. 6867- 6880 ,(1970) , 10.1021/JA00726A025
Arthur S. Werner, Tomas Baer, Absolute unimolecular decay rates of energy selected C4H6+metastable ions The Journal of Chemical Physics. ,vol. 62, pp. 2900- 2910 ,(1975) , 10.1063/1.430828