5.19 Addition Reaction: 1,4 Addition Heteroatom
作者： M. Kawatsura , T. Itoh
DOI: 10.1016/B978-0-08-095167-6.00521-8
关键词: Nucleophile 、 Transition metal 、 Addition reaction 、 Combinatorial chemistry 、 Thio- 、 Michael reaction 、 Heteroatom 、 Catalysis 、 Chemistry 、 Amine gas treating 、 Organic chemistry
摘要: Asymmetric 1,4-addition of amine, thiols, phosphite, or nucleophilic silicone to α , β -unsaturated substrates is regarded as efficient, atom-economical, and powerful reactions for the preparation corresponding chiral -amino-, -thio-, -phosphonylate-, -silyl-compounds. Recently, significant progress has been made in field organocatalyst transition metal-catalyzed asymmetric reactions. In this chapter, authors focus on reviewing recent regarding syntheses optically active -substituted compounds through using organocatalysts metal catalysts.
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