On PAH formation in strained counterflow diffusion flames
作者： H Böhm , K Kohse-Höinghaus , F Lacas , C Rolon , N Darabiha
DOI: 10.1016/S0010-2180(00)00188-7
关键词: Diffusion (business) 、 Diffusion flame 、 Strain (chemistry) 、 Flame structure 、 Chemical physics 、 Organic chemistry 、 Soot 、 Reaction mechanism 、 Methane 、 Benzene 、 Chemistry
摘要: The structural response of methane/air and methane-nitrogen/air counterflow diffusion flames to strain was investigated by measurements computations. numerical predictions were found be in reasonably good agreement with the experiments. Different reaction pathways leading PAH formation are examined computationally obtain a deeper understanding process soot precursor strained flames. Both experimental computational results indicate that concentration C2H2 C3H3, as well PAH, candidates for formation, diminish increasing rates. decrease is caused depletion benzene precursors. In looking find control parameters reactive flows, it suggested image rates based on CH2O, respectively CHO, ratio.
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