Cu-based carbene involved in a radical process: a new crossover reaction to construct γ-peroxy esters and 1,4-dicarbonyl compounds.
作者： Jiewen Jiang , Jiajun Liu , Ling Yang , Ying Shao , Jiang Cheng
DOI: 10.1039/C5CC05183E
关键词: Crossover 、 Transition metal carbene complex 、 Coupling reaction 、 Scientific method 、 Radical 、 Carbene 、 Organic chemistry 、 High selectivity 、 Volume concentration 、 Combinatorial chemistry 、 Chemistry
摘要: Through merging Cu-based carbenes in a radical process, novel crossover reaction has been successfully established, leading to the facile and efficient syntheses of various γ-peroxy esters 1,4-dicarbonyl compounds. Considering that both carbene complexes radicals are extremely reactive, therefore exist only extraordinarily low concentrations, high selectivity this coupling is unusual.
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