The Suzuki-Miyaura reaction
作者： Ivica Cepanec
DOI: 10.1016/B978-008044412-3/50006-3
关键词: Organoboron compounds 、 Halide 、 Grignard reaction 、 Chemistry 、 Aryl 、 Electrophile 、 Organic chemistry
摘要: The cross-coupling reactions of a wide variety organoboron compounds with aryl halides and similar substrates, such as sulfonates or some other electrophilic to produce alkenes, arylalkenes, alkylarenes, biaryls are well known the Suzuki–Miyaura (SM) reaction, which due its general applicability efficiency has become most important C–C bond-forming “Grignard reaction 21 st century.” applications in synthesis discussed this chapter. SM includes arylboronic acids esters (Ar – X, X = I, Br, C1), (ArOTf OMs), diazonium salts (ArN 2 + BF 4 ), proceeds smoothly give corresponding good excellent yields.
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