Geochemistry and age of groundwater in a hydrochemically diversified aquifer (Permo-Carboniferous, the Intra- Sudetic Synclinorium, SW Poland) derived from geochemical modelling and isotopic studies
作者： Dariusz Dobrzynski
DOI:
关键词: Dolomite 、 Stable isotope ratio 、 Aquifer 、 Radiocarbon dating 、 Mineral water 、 Geology 、 Geochemistry 、 Calcite 、 Sedimentary rock 、 Groundwater
摘要: Comprehensive investigations of groundwater were performed in a sedimentary aquifer Permo-Carboniferous, Intra-Sudetic Synclinorium, SWPoland. The investigation included aqueous chemical and isotopic composition, chemistry mineral phases, geochemical modelling, tritium radiocarbon dating. Chemical diversity the system is created by mixing modern fresh water older sulphate with higher dissolved solids. treated as flows two end-member types. Geochemical modelling used for: (1) explaining origin chemistry both components, (2) quantifying the groundwater mixing, (3) correcting age for effects water-rock interactions, (4) calculating reaction rates. Study stable (C, S, O, H) unstable ( 3 H, 14 C) isotopes allowed the inverse mass balance models to be verified specified, dated. The modern, tritium-bearing, result dissolution limestones, dolomites and gypsum. mean tritium-age this water, based on lumped-parameter approach, varies between 10 and 200 years. owes its process dedolomitization driven gypsum dissolution. Its about 5.9 ka BP, i.e., during Mid-Holocene Climatic Optimum. Rates of reactions responsible formation type are estimated be: gypsum (2.85 μmol/L/year) dolomite (0.21 μmol/L/year), calcite precipitation (0.20 organic matter decomposition (0.08 μmol/L/year).
pgi.gov.pl参考文章(88)
Mariusz Orion Jådrysek, Oxygen and Sulphur Isotope Dynamics in the SO42- of an Urban Precipitation Water Air and Soil Pollution. ,vol. 117, pp. 15- 25 ,(2000) , 10.1023/A:1005199521493
BALANCE : a computer program for calculating mass transfer for geochemical reactions in ground water Water-Resources Investigations Report. ,(1982) , 10.3133/WRI8214
H. Roy Krouse, Bernhard Mayer, Sulphur and Oxygen Isotopes in Sulphate Environmental Tracers in Subsurface Hydrology. pp. 195- 231 ,(2000) , 10.1007/978-1-4615-4557-6_7
Geochemical and isotopic composition of ground water with emphasis on sources of sulfate in the upper Floridan Aquifer and intermediate aquifer system in southwest Florida Water-Resources Investigations Report. ,(1996) , 10.3133/WRI964146
Marek Awdankiewicz, Volcanism in a late Variscan intramontane trough: the petrology and geochemistry of the Carboniferous and Permian volcanic rocks of the Intra-Sudetic Basin, SW Poland Geologia Sudetica. ,vol. 32, pp. 83- 111 ,(1999)
An interactive code (NETPATH) for modeling NET geochemical reactions along a flow PATH Water-Resources Investigations Report. ,(1991) , 10.3133/WRI914078
Marek Duliński, Jerzy Grabczak, Kazimierz Różański, Tadeusz Florkowski, 25 lat systematycznych pomiarów składu izotopowego opadów na terenie Polski Przegląd Geologiczny. ,vol. 49, pp. 250- 256 ,(2001)
Quan Hua, Mike Barbetti, Review of Tropospheric Bomb 14C Data for Carbon Cycle Modeling and Age Calibration Purposes Radiocarbon. ,vol. 46, pp. 1273- 1298 ,(2004) , 10.1017/S0033822200033142
Phreeqe--A Computer Program for Geochemical Calculations Water-Resources Investigations Report. ,(1980) , 10.3133/WRI8096
Dariusz Dobrzyński, Chemical diversity of groundwater in the Carboniferous-Permian aquifer in the Unisław Śląski - Sokołowsko area (the Sudetes, Poland); a geochemical modelling approach Acta Geologica Polonica. ,vol. 57, pp. 97- 112 ,(2007)