Development of New Hydrogenations of Imines and Benign Reductive Hydroaminations: Zinc Triflate as a Catalyst
作者： Svenja Werkmeister , Steffen Fleischer , Shaolin Zhou , Kathrin Junge , Matthias Beller
关键词: Organic chemistry 、 Hydroamination 、 Zinc 、 Chemistry 、 Catalysis 、 Trifluoromethanesulfonate
摘要: The hydrogenation of imines to amines in the presence catalytic amounts zinc triflate has been demonstrated for first time. In addition, an efficient procedure reductive hydroamination alkynes is presented using as a catalyst precursor. both protocols variety different functional groups are tolerated, and reactions proceed smoothly high yields.
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