Atmospheric Reaction Mechanisms of Amine Fuels
作者： Ernesto C. Tuazon , William P. L. Carter , Roger Atkinson , Arthur M. Winer , Richard V. Brown
DOI:
关键词: Spectroscopy 、 Ozone 、 Dimethylhydrazine 、 Chemical kinetics 、 Amine gas treating 、 Inorganic chemistry 、 Infrared spectroscopy 、 Photochemistry 、 Hydrazine 、 Monomethylhydrazine 、 Chemistry
摘要: Abstract : This report describes a detailed investigation of the atmospheric reactions hydrazine (N2H4), monomethylhydrazine (MMH), and unsymmetrically dimethylhydrazine (UDMH) relevant to assessments impact their releases atmosphere as result wide use fuels for military purposes. Experiments were conducted in 3800 l 6400 Teflon reaction chambers, with reactant product concentrations measured by long pathlength (68.3-102.4 m) Fourier transform infrared (FT-IR) spectroscopy.
参考文章(21)
Richard A. Cox, Michael J. Roffey, Thermal decomposition of peroxyacetylnitrate in the presence of nitric oxide Environmental Science & Technology. ,vol. 11, pp. 900- 906 ,(1977) , 10.1021/ES60132A010
Rao CNR., Chemical Applications of Infrared Spectroscopy ,(1963)
Robert F. Hampson, Chemical kinetic and photochemical data sheets for atmospheric reactions ,(1980)
MICHEL A. SAAD, MICHAEL B. DETWEILER, MICHAEL A. SWEENEY, Analysis of Reaction Products of Nitrogen Tetroxide with Hydrazines under Nonignition Conditions AIAA Journal. ,vol. 10, pp. 1073- 1078 ,(1972) , 10.2514/3.50297
R. Atkinson, R. A. Perry, J. N. Pitts, Rate constants for the reactions of the OH radical with (CH3)2NH, (CH3)3N, and C2H5NH2 over the temperature range 298–426 °K The Journal of Chemical Physics. ,vol. 68, pp. 1850- 1853 ,(1978) , 10.1063/1.435906
Roger Atkinson, William P. L. Carter, Arthur M. Winer, James N. Pitts, An Experimental Protocol for the Determination of OH Radical Rate Constants with Organics Using Methyl Nitrite Photolysis as an OH Radical Source Journal of the Air Pollution Control Association. ,vol. 31, pp. 1090- 1092 ,(1981) , 10.1080/00022470.1981.10465331
Richard A. Graham, Arthur M. Winer, James N. Pitts, Temperature dependence of the unimolecular decomposition of pernitric acid and its atmospheric implications Chemical Physics Letters. ,vol. 51, pp. 215- 220 ,(1977) , 10.1016/0009-2614(77)80387-4
Ernesto C. Tuazon, William P. L. Carter, Arthur M. Winer, James N. Pitts, Reactions of hydrazines with ozone under simulated atmospheric conditions Environmental Science & Technology. ,vol. 15, pp. 823- 828 ,(1981) , 10.1021/ES00089A008
Vernon H. Dibeler, J. L. Franklin, Robert M. Reese, Electron Impact Studies of Hydrazine and the Methyl-substituted Hydrazines1 Journal of the American Chemical Society. ,vol. 81, pp. 443- 457 ,(1959) , 10.1021/JA01510A015
S. N. Foner, R. L. Hudson, Mass Spectrometric Detection of Triazene and Tetrazene and Studies of the Free Radicals NH2 and N2H3 Journal of Chemical Physics. ,vol. 29, pp. 442- 443 ,(1958) , 10.1063/1.1744501