Anionic Polymerization: Recent Advances
作者： Robert Jérôme , Philippe Teyssié
DOI: 10.1002/9783527603978.MST0229
关键词: Reversible addition−fragmentation chain-transfer polymerization 、 Cationic polymerization 、 Polymer chemistry 、 Anionic addition polymerization 、 Living polymerization 、 Polymerization 、 Chemistry 、 Chain transfer 、 Living anionic polymerization 、 Ionic polymerization
摘要: The sections in this article are Introduction General Aspects of Anionic Living Polymerization Strategies Group Transfer Polymerization A Discussed Mechanism A Remarkable Macromolecular Architecture Metal-Free Polymerization Nucleophilic/Coordinative Polymerization Organolanthanides (III)-Initiated Polymerization Metalloporphyrin-Mediated Nucleophilic Polymerizations “Ligated” Polymerization Ion-Pairs Complexation: Nature Ligands Effect Ligands on Thermodynamics Coordination Strength σ-Chelating Ligands Steric Hindrance around the “Ligated” Ion-Pairs Effect Kinetics Modification Association Equilibria Modification Solvation Equilibria A Golden Tool for Engineering Conclusions
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