Prediction of chlor-alkali’s caustic current efficiency by artificial neural network; case study: A zero-gap advanced chlor-alkali cell

作者: E. Joudaki , F. Mohammadi , A. Yousefi , T. Mirzazadeh

DOI: 10.5004/DWT.2009.669

关键词: Electrical engineeringArtificial neural networkAnodeEngineeringCathodeCurrent (fluid)Current densityProcess engineeringMinimum mean square errorCaustic (optics)Volumetric flow rate

摘要: The progress of the membrane chlor-alkali technology resulted in a meaningful reduction energy consumption process. In this research at first step, zero-gap oxygendepolarized cell with state-of-the-art silver plated nickel screen electrode (ESNS®) was employed to consider effects various process parameters on caustic current efficiency. anode side anolyte pH, temperature, flow rate brine concentration and cathode oxygen rate, applied density are taken as parameters. At second step pre-scaled experimental data were used train artificial neural networks (ANNs). ANNs approach is estimate efficiency (CCE). training back-propagation learning algorithm several methods used. minimum error found be that Levenberg-Marquardt (LM) algorithm. Excellent prediction mean square 1.1e–4 made. The...

参考文章(19)
Lajos Végvári, András Tompos, Sándor Gőbölös, József Margitfalvi, Holographic research strategy for catalyst library design: Description of a new powerful optimisation method Catalysis Today. ,vol. 81, pp. 517- 527 ,(2003) , 10.1016/S0920-5861(03)00150-0
F Federico, G N Martelli, D Pinter, Gas-Diffusion Electrodes for Chlorine-Related (Production) Technologies Modern Chlor-Alkali Technology. pp. 114- 127 ,(2007) , 10.1002/9780470999479.CH9
R. Beale, T. Jackson, Neural Computing - An Introduction ,(1990)
Howard B. Demuth, Martin T. Hagan, Mark Beale, Neural network design ,(1995)
Y. Xiong, L. Jialing, S. Hong, Bubble effects on ion exchange membranes — an electrochemical study Journal of Applied Electrochemistry. ,vol. 22, pp. 486- 490 ,(1992) , 10.1007/BF01077554
Farhat Aziz, Ghazanfar A. Mirza, Spectrophotometric determination of hydrogen peroxide in alkaline solution Talanta. ,vol. 11, pp. 889- 892 ,(1964) , 10.1016/0039-9140(64)80117-X
G. Padmavathi, M.G. Mandan, S.P. Mitra, K.K. Chaudhuri, Neural modelling of Mooney viscosity of polybutadiene rubber Computers & Chemical Engineering. ,vol. 29, pp. 1677- 1685 ,(2005) , 10.1016/J.COMPCHEMENG.2005.02.028
Nagakazu Furuya, Hiroaki Aikawa, Comparative study of oxygen cathodes loaded with Ag and Pt catalysts in chlor-alkali membrane cells Electrochimica Acta. ,vol. 45, pp. 4251- 4256 ,(2000) , 10.1016/S0013-4686(00)00557-0
Gholamreza Zahedi, Abdolhossein Jahanmiri, M. R. Rahimpor, A Neural Network Approach for Prediction of the CuO-ZnO-Al2O3 Catalyst Deactivation International Journal of Chemical Reactor Engineering. ,vol. 3, ,(2005) , 10.2202/1542-6580.1187