(3+3)-Annulation of Carbonyl Ylides with Donor-Acceptor Cyclopropanes: Synergistic Dirhodium(II) and Lewis Acid Catalysis.

作者: Martin Petzold , Peter G. Jones , Daniel B. Werz

DOI: 10.1002/ANIE.201814409

关键词: CycloadditionPyranMedicinal chemistryReactivity (chemistry)ChemistryCatalysisLewis acid catalysisSynergistic catalysisDiazoAnnulation

摘要: Abstract The first (3+ 3)‐annulation process of donor–acceptor cyclopropanes using synergistic catalysis is reported. The Rh2 (OAc) 4‐catalyzed decomposition of diazo …

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