Energetic Al/Fe2O3/PVDF composites for high energy release: Importance of polymer binder and interface

作者: Jae Hun Lee , Sang Jin Kim , Jung Soo Park , Jong Hak Kim

DOI: 10.1007/S13233-016-4117-2

关键词: HydrocarbonCompression moldingAluminiumMaterials scienceExothermic reactionPolymerFluorocarbonReactive materialIron oxideComposite material

摘要: Energetic composite materials are very important in military purpose and building explosion but, the role of polymer binder interfaces has been little reported. Here, we prepared energetic composites consisting aluminum (Al), iron oxide (Fe2O3) polymer, as fuel, oxidizer binder, respectively. Two different methods, i.e. physical mixing compression molding were employed to form blended powder film, The use partially fluorinated such poly(vinylidene fluoride) (PVDF) resulted large improvement exothermic energy compared that hydrocarbon poly(vinyl pyrrolidone) (PVP), representing fluorocarbon groups actively involved reaction PVDF acts an well binder. Furthermore, Al/Fe2O3/PVDF film by exhibited much higher than powder, indicating importance intimate contact property for release. Open image new window

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