In situ fabrication of graphene decorated microstructured globe artichokes of partial molar nickel cobaltite anchored on a Ni foam as a high-performance supercapacitor electrode

作者: Pinjari Syedvali , Gaddam Rajeshkhanna , Ediga Umeshbabu , Gundla Uday Kiran , G. Ranga Rao

DOI: 10.1039/C5RA03463A

关键词: CobaltiteNickelPseudocapacitanceElectrodeCurrent densitySupercapacitorGrapheneChemical engineeringMaterials scienceNanotechnologyCapacitance

摘要: By taking advantage of the splendid properties graphene (electrical conductivity) and transition metal oxides (pseudocapacitance nature), we have in situ fabricated novel microstructured globe artichokes a rGO/Ni0.3Co2.7O4 composite on nickel foam through simple surfactant free hydrothermal method followed by calcination process. The artichoke flower-like morphology is constructed hundreds self-assembled micropetals interconnected with several layers circles at base to form microspheres uniform dimension. as-obtained enhanced stability electrochemical performance hybrid electrode due its unique structure. Therefore, synergetic effects structure thus made binder allows better charge transport exhibits superb specific capacitance areal 1624 F g−1 2.37 cm−2 current density 2 A g−1. Moreover, increases from 1088 1728 end 7000 cycles, which indicates that material becomes active cycling. Furthermore, when power increased 16 times i.e. 0.5 8 kW kg−1 energy sinks 40 56.39 W h (i.e., 29% reduction only), suggesting remarkable for supercapacitor applications.

参考文章(59)
J. R. Miller, P. Simon, Electrochemical Capacitors for Energy Management Science. ,vol. 321, pp. 651- 652 ,(2008) , 10.1126/SCIENCE.1158736
Grace Wee, Huan Zhong Soh, Yan Ling Cheah, Subodh G. Mhaisalkar, Madhavi Srinivasan, Synthesis and electrochemical properties of electrospun V2O5 nanofibers as supercapacitor electrodes Journal of Materials Chemistry. ,vol. 20, pp. 6720- 6725 ,(2010) , 10.1039/C0JM00059K
Changzhou Yuan, Jiaoyang Li, Linrui Hou, Xiaogang Zhang, Laifa Shen, Xiong Wen David Lou, Ultrathin Mesoporous NiCo2O4Nanosheets Supported on Ni Foam as Advanced Electrodes for Supercapacitors Advanced Functional Materials. ,vol. 22, pp. 4592- 4597 ,(2012) , 10.1002/ADFM.201200994
P. Ragupathy, Dae Hoon Park, Guy Campet, H. N. Vasan, Seong-Ju Hwang, Jin-Ho Choy, N. Munichandraiah, Remarkable capacity retention of nanostructured manganese oxide upon cycling as an electrode material for supercapacitor Journal of Physical Chemistry C. ,vol. 113, pp. 6303- 6309 ,(2009) , 10.1021/JP811407Q
P. Justin, Sumanta Kumar Meher, G. Ranga Rao, Tuning of Capacitance Behavior of NiO Using Anionic, Cationic, and Nonionic Surfactants by Hydrothermal Synthesis Journal of Physical Chemistry C. ,vol. 114, pp. 5203- 5210 ,(2010) , 10.1021/JP9097155
Subbukalai Vijayakumar, Sadayappan Nagamuthu, Gopalan Muralidharan, Supercapacitor studies on NiO nanoflakes synthesized through a microwave route. ACS Applied Materials & Interfaces. ,vol. 5, pp. 2188- 2196 ,(2013) , 10.1021/AM400012H
Yanwu Zhu, Shanthi Murali, Weiwei Cai, Xuesong Li, Ji Won Suk, Jeffrey R Potts, Rodney S Ruoff, None, Graphene and Graphene Oxide: Synthesis, Properties, and Applications Advanced Materials. ,vol. 22, pp. 3906- 3924 ,(2010) , 10.1002/ADMA.201001068
Nae-Lih Wu, Shi-Yu Wang, Chih-Yu Han, Dien-Shi Wu, Lih-Ren Shiue, Electrochemical capacitor of magnetite in aqueous electrolytes Journal of Power Sources. ,vol. 113, pp. 173- 178 ,(2003) , 10.1016/S0378-7753(02)00482-2
Ye Shi, Lijia Pan, Borui Liu, Yaqun Wang, Yi Cui, Zhenan Bao, Guihua Yu, Nanostructured conductive polypyrrole hydrogels as high-performance, flexible supercapacitor electrodes J. Mater. Chem. A. ,vol. 2, pp. 6086- 6091 ,(2014) , 10.1039/C4TA00484A
Qi Lu, Jingguang G. Chen, John Q Xiao, Nanostructured electrodes for high-performance pseudocapacitors. Angewandte Chemie. ,vol. 52, pp. 1882- 1889 ,(2013) , 10.1002/ANIE.201203201