Method for polymerizing vinyl monomers in a coated reactor

作者: Mikio C , O Enbi Gijutsu Kenkyusho Watanabe , O Enbi Gijutsu Kenkyusho Shimizu , Genji c , o Enbi Gijutsu Kenkyusho Noguki

DOI:

关键词: MonomerConjugated systemPolymer chemistryPolymerMaterials scienceReagentCoatingPolymerizationColloidDouble bond

摘要: A process for producing a polymer by polymerizing in polymerization vessel monomer having an ethylenic double bond is provided. In this process, the has scale preventive coating film on its inner wall surfaces and other with which comes into contact during polymerization. The formed liquid containing (A) compound selected from group consisting of aromatic 5 or more conjugated π bonds heterocyclic bonds, (B) inorganic colloid, chelate reagent, metal that produces ion capable forming complex at least two coordination numbers, acid; being coated means steam as carrier. This can shorten time films agents to improve productivity, effect preventing scales, make colored particles less mix products, lessen fish eyes initial discoloring products quality polymeric their molded products.

参考文章(3)
Toshihide Shimizu, Mikio Watanabe, Polymer scale preventive agent ,(1993)
Donald Edward Witenhafer, Richard Kenneth Miller, James Richard Norris, Process for coating reactors using steam application ,(1979)