High performance inorganic complexes for next-generation redox flow batteries
作者： Robert H. Grubbs , Harry B. Gray , Emmanuelle Despagnet-ayoub , Brendon Mcnicholas , Simon C. Jones
DOI:
关键词: Redox 、 Functional group 、 Metal 、 Coordination sphere 、 Solvent 、 Flow battery 、 Chemistry 、 Combinatorial chemistry 、 Ligand 、 Lewis acids and bases
摘要: In an aspect, a redox flow battery comprises catholyte and anolyte; wherein at least one of said anolyte is metal-coordination complex, complex comprising: (i) metal; (ii) or more first ligands coordinated with metal atom, each independently Lewis basic ligand; second associated ligands, acid nonaqueous solvent, catholyte, both are dissolved in solvent. One may be provided primary coordination sphere secondary complex. The comprise functional group acidic group.
lens.org 参考文章(34)
Paul T. Anastas, Samuel L. Collom, Robert H. Crabtree, Aaron J. Bloomfield, Stafford W. Sheehan, Metal oxide-organic hybrid materials for heterogeneous catalysis and methods of making and using thereof ,(2014)
Ke Gong, Qianrong Fang, Shuang Gu, Sam Fong Yau Li, Yushan Yan, Nonaqueous redox-flow batteries: organic solvents, supporting electrolytes, and redox pairs Energy and Environmental Science. ,vol. 8, pp. 3515- 3530 ,(2015) , 10.1039/C5EE02341F
Joung-Won Park, Hee-young Sun, Seung-uk Son, Doo-yeon Lee, Organic electrolyte solution and redox flow battery including the same ,(2011)
Chad Staiger, Harry Pratt, Travis Mark Anderson, David Ingersoll, Synthesis of electroactive ionic liquids for flow battery applications ,(2012)
John J. Alexander, Harry B. Gray, Electronic structures of hexacyanometalate complexes Journal of the American Chemical Society. ,vol. 90, pp. 4260- 4271 ,(1968) , 10.1021/JA01018A013
Allen J Bard, Larry R Faulkner, Henry S White, Electrochemical Methods: Fundamentals and Applications ,(1980)
W. Steffen, K. Richardson, J. Rockstrom, S. E. Cornell, I. Fetzer, E. M. Bennett, R. Biggs, S. R. Carpenter, W. de Vries, C. A. de Wit, C. Folke, D. Gerten, J. Heinke, G. M. Mace, L. M. Persson, V. Ramanathan, B. Reyers, S. Sorlin, Planetary boundaries: Guiding human development on a changing planet Science. ,vol. 347, pp. 1259855- 1259855 ,(2015) , 10.1126/SCIENCE.1259855
Igor B. Sivaev, Vladimir I. Bregadze, Lewis acidity of boron compounds Coordination Chemistry Reviews. ,vol. 270, pp. 75- 88 ,(2014) , 10.1016/J.CCR.2013.10.017
Gerard T. Rowe, Elena V. Rybak-Akimova, John P. Caradonna, Unraveling the Reactive Species of a Functional Non-Heme Iron Monooxygenase Model Using Stopped-Flow UV−Vis Spectroscopy Inorganic Chemistry. ,vol. 46, pp. 10594- 10606 ,(2007) , 10.1021/IC7011217
Adam Z. Weber, Matthew M. Mench, Jeremy P. Meyers, Philip N. Ross, Jeffrey T. Gostick, Qinghua Liu, Redox flow batteries: a review Journal of Applied Electrochemistry. ,vol. 41, pp. 1137- 1164 ,(2011) , 10.1007/S10800-011-0348-2