Ruspolia hypercrateriformisM.R.: Isolierung und Strukturaufklärung von neuen Pyrrolidin‐Alkaloiden. 169. Mitt. über organische Naturstoffe

作者: Felix Roessler , Dietmar Ganzinger , Siegfried Johne , Emanuel Schöpp , Manfred Hesse

DOI: 10.1002/HLCA.19780610336

关键词: Organic chemistryChemical transformationStereochemistryPyrrolidineChemistryAcanthaceae

摘要: Ruspolia hypercrateriformisM.R.: Isolation and Structure Elucidation of New Pyrrolidine Alkaloids Three new pyrrolidine alkaloids have been isolated from hypercrateriformis, which belongs to the plant family Acanthaceae. The structure ruspolinone (1), norruspolinone (2) norruspoline (3) (Scheme 1) has elucidated by means spectroscopic data pure compounds their derivatives, chemical transformation fo 2 1 methylation, trans-formation 3 identical hydrogenation products, comparison degradation products with synthetically prepared model compounds.

参考文章(5)
N.B. Mulchandani, S.S. Iyer, L.P. Badheka, Incorporation of tyrosine-2-14C into tylophorine Phytochemistry. ,vol. 8, pp. 1931- 1935 ,(1969) , 10.1016/S0031-9422(00)88079-6
R. Lukeš, J. Kovář, J. Kloubek, K. Bláha, Zur konfiguration stickstoffhaltiger verbindungen VII. Absolute konfiguration von hydrin und hydrolin Collection of Czechoslovak Chemical Communications. ,vol. 25, pp. 483- 491 ,(1960) , 10.1135/CCCC19600483
JW Loder, Synthesis of Pleurospermine, the Leaf Alkaloid of Cryptocarya pleurosperma White and Francis Australian Journal of Chemistry. ,vol. 15, pp. 296- 300 ,(1962) , 10.1071/CH9620296