Unique formation of two high-nuclearity metallamacrocycles from a mononuclear complex [Zn(dmpzdtc)2] (dmpzdtc = 3,5-dimethylpyrazole-1-dithiocarboxylate) via CS2 elimination
作者： Hong-Xi Li , Hua-Zhou Wu , Wen-Hua Zhang , Zhi-Gang Ren , Yong Zhang
DOI: 10.1039/B710787K
关键词: Dissolution 、 Stereochemistry 、 Medicinal chemistry 、 Chemistry
摘要: Dissolution of a mononuclear complex [Zn(dmpzdtc)2] in BrCH2CH2Br or DMF saturated with water followed by CS2 elimination led to the formation two unique high-nuclearity metallamacrocyclic complexes, [Zn4(μ-dmpz)6(μ-OH)2]2 and [Zn4(μ-dmpz)6(μ-OH)2]4.
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