Chemical Considerations in the Incineration of Chlorinated Methanes I-Methyl Chloride

摘要: ABSTRACT The high temperature product distributions from reactions of methane and methyl chloride have been measured under pyrolysis, preignition oxidation flame conditions. For pyrolysis data, 3% fuel/zero oxygen or stoichiometric oxygen/10% N2/Ar were heated behind reflected shocks to temperatures between 1200-2600 K at a density approximately 2.5 ± 0.25 × 10−5 mol/cm3. Flame studies conducted atmospheric pressure for methane/air chloride/methane/air mixtures with equivalence ratios 1.15 1.35 four chloride/methane ranging pure chloride. Methyl is more easily decomposed than in either oxidation. This because the lower bond dissociation energy (Do (CH3-Cl) = 334 kJ/mol) as compared (Do(CH3-H) 435 kJ/mol). In environment, disappear same rate. presence chlorine d...