Effect of Deuterium Substitution on the Lifetime of the Phosphorescent Triplet State of Naphthalene
作者： Clyde A. Hutchison , Billy W. Mangum
DOI: 10.1063/1.1730887
关键词: Atomic physics 、 Paramagnetism 、 Deuterium 、 Hyperfine structure 、 Exponential decay 、 Nuclear magnetic resonance 、 Chemistry 、 Resonance 、 Half-life 、 Durene 、 Triplet state
摘要: Deuterated naphthalene in deuterated durene (DD) was observed to have an extraordinarily intense paramagnetic resonance signal relative ordinary (HH). Decays of the magnetic resonances after cessation ultraviolet irradiation were examined at 77 deg K and found obey exponential decay law with a mean life 2.1 plus or minus 0.1 sec for HH 16.9 0.7 DD. The (HD) differ by less than 0.5 from that HH. also studied static field along two principal axes all three variation lifetime direction nil. showing change lifetinne is purely mass effect rather nuclear hyperfine effect. (D.L.C.)
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sci-hub.se 参考文章(2)
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Clyde A. Hutchison, Billy W. Mangum, Paramagnetic Resonance Absorption in Naphthalene in Its Phosphorescent State The Journal of Chemical Physics. ,vol. 29, pp. 952- 953 ,(1958) , 10.1063/1.1744621