A novel microfluidic device for fast extraction of polycyclic aromatic hydrocarbons (PAHs) from environmental waters – comparison with stir-bar sorptive extraction (SBSE)

作者: Louise Foan , Florence Ricoul , Séverine Vignoud

DOI: 10.1080/03067319.2014.994617

关键词: Bar (unit)Water Framework DirectivePollutantLow volumeExtraction (chemistry)DesorptionChromatographyChemistryEnvironmental chemistryMicrofluidicsDrinking water directive

摘要: Polycyclic aromatic hydrocarbons (PAHs) are persistent organic pollutants renowned for their ubiquity in the environment and potential carcinogenicity. To verify compliance to European Drinking Water Directive (98/83/EC) Framework (2000/60/EC), these compounds have be monitored environmental waters. Conventional laboratory analysis implies important costs labour, may lead low sample representativeness due sampling, transport storage prior analysis. date, no portable equipment enables situ PAH determination with adequate selectivity sensitivity. build a cost-effective high-performance system, microfluidic device fast extraction of PAHs volume samples has been developed tested by solvent desorption. Pre-concentration recoveries were evaluated liquid chromatography associated multi-wavelength fluorescence detection (HPLC-FLD). The operational parameters optimised 5 µg L−1 spiked ...

参考文章(41)
V.M. León, J. Llorca-Pórcel, B. Álvarez, M.A. Cobollo, S. Muñoz, I. Valor, Analysis of 35 priority semivolatile compounds in water by stir bar sorptive extraction–thermal desorption–gas chromatography–mass spectrometry: Part II: Method validation Analytica Chimica Acta. ,vol. 558, pp. 261- 266 ,(2006) , 10.1016/J.ACA.2005.10.080
A. Prieto, O. Telleria, N. Etxebarria, L.A. Fernández, A. Usobiaga, O. Zuloaga, Simultaneous preconcentration of a wide variety of organic pollutants in water samples: Comparison of stir bar sorptive extraction and membrane-assisted solvent extraction Journal of Chromatography A. ,vol. 1214, pp. 1- 10 ,(2008) , 10.1016/J.CHROMA.2008.10.060
Philipp Mayer, Lars Toräng, Nadia Glæsner, Jan Åke Jönsson, Silicone Membrane Equilibrator: Measuring Chemical Activity of Nonpolar Chemicals with Poly(dimethylsiloxane) Microtubes Immersed Directly in Tissue and Lipids Analytical Chemistry. ,vol. 81, pp. 1536- 1542 ,(2009) , 10.1021/AC802261Z
Brigitte Niehus, Peter Popp, Coretta Bauer, Gisela Peklo, Heinz W. Zwanziger, Comparison of Stir Bar Sorptive Extraction and Solid Phase Extraction as Enrichment Techniques in Combination with Column Liquid Chromatography for the Determination of Polycyclic Aromatic Hydrocarbons in Water Samples International Journal of Environmental Analytical Chemistry. ,vol. 82, pp. 669- 676 ,(2002) , 10.1080/0306731021000075393