Post-functionalization of graphitic carbon nitrides by grafting organic molecules: toward C-H bond oxidation using atmospheric oxygen.

作者: Pengfei Zhang , Haoran Li , Yong Wang

DOI: 10.1039/C4CC02676D

关键词: Graphitic carbonInorganic chemistryNitrideAtmospheric oxygenGraftingGraphitic carbon nitridePolymerChemical engineeringCarbonSurface modificationMaterials science

摘要: Described here is the feasible modification of a graphitic carbon nitride polymer using Prato's reaction with in situ formed azomethine ylides. These novel nitrides designable organic functional groups, and tailorable surface structure properties illustrated excellent performance selective oxidation 3,5,5-trimethylcyclohex-3-en-1-one atmospheric oxygen.

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