Characterization of Rigid Polyurethane Foam Prepared from Recycling of PET Waste

作者: Abolfazl Ghaderian , Amir Hossein Haghighi , Faramarz Afshar Taromi , Zizi Abdeen , Ali Boroomand

DOI: 10.3311/PPCH.7801

关键词: PolyolMaterials sciencePolyvinyl alcoholChemical engineeringBlowing agentEthyleneOrganic chemistryPolyurethaneMethylene diphenyl diisocyanateThermal stabilityPolymer

摘要: Poly (ethylene terephthalate) (PET) waste bottles were recycled to prepare RPUFs (rigid polyurethane foams) by using propylene glycol (PG) in different glycol/polymer molar ratios. The glycolysis products characterized, after that, they reacted with poly methylene diphenyl diisocyanate (PMDI) the presence of blowing, co-blowing and second blowing agents produce RPUFs. prepared foams characterized compared foam that is produced original polyol. It was found have possibility for fabrication proper properties depending on agent type density, also similar thermal stability one This may provide an advantage future planning recycling PET enhance mechanical PU.

参考文章(26)
Abdel Azim A. Abdel Azim, Ayman M. Atta, R.A. El-Ghazawy, Synthesis of rigid polyurethane foams from recycled poly(ethylene terephthalate) waste Cellular Polymers. ,vol. 25, pp. 35- 48 ,(2006) , 10.1177/026248930602500103
George P Karayannidis, Dimitris S Achilias, None, Chemical Recycling of Poly(ethylene terephthalate) Macromolecular Materials and Engineering. ,vol. 292, pp. 128- 146 ,(2007) , 10.1002/MAME.200600341
Vassilis A Kosmidis, Dimitris S Achilias, George P Karayannidis, None, Poly(ethylene terephthalate) Recycling and Recovery of Pure Terephthalic Acid. Kinetics of a Phase Transfer Catalyzed Alkaline Hydrolysis Macromolecular Materials and Engineering. ,vol. 286, pp. 640- 647 ,(2001) , 10.1002/1439-2054(20011001)286:10<640::AID-MAME640>3.0.CO;2-1
Hao-Hong Zhang, Hong-Wei Xiang, Yong Yang, Yuan-Yuan Xu, Yong-Wang Li, Depolymerization of poly(trimethylene terephthalate) in supercritical methanol Journal of Applied Polymer Science. ,vol. 92, pp. 2363- 2368 ,(2004) , 10.1002/APP.13713
Guoxi Xi, Maixi Lu, Chen Sun, None, Study on depolymerization of waste polyethylene terephthalate into monomer of bis(2-hydroxyethyl terephthalate) Polymer Degradation and Stability. ,vol. 87, pp. 117- 120 ,(2005) , 10.1016/J.POLYMDEGRADSTAB.2004.07.017
Takeshi Sako, Idzumi Okajima, Tsutomu Sugeta, Katsuto Otake, Satoshi Yoda, Yoshihiro Takebayashi, Chiyoshi Kamizawa, Recovery of constituent monomers from polyethylene terephthalate with supercritical methanol Polymer Journal. ,vol. 32, pp. 178- 181 ,(2000) , 10.1295/POLYMJ.32.178
Utpal R. Vaidya, Vikas M. Nadkarni, Unsaturated polyester resins from poly(ethylene terephthalate) waste. 2. Mechanical and dynamic mechanical properties Industrial & Engineering Chemistry Research. ,vol. 27, pp. 2056- 2060 ,(1988) , 10.1021/IE00083A016
J.L. Rivera-Armenta, Th. Heinze, A.M. Mendoza-Martínez, New polyurethane foams modified with cellulose derivatives European Polymer Journal. ,vol. 40, pp. 2803- 2812 ,(2004) , 10.1016/J.EURPOLYMJ.2004.07.015