Cationic complexes of the ‘3+1’ oxorhenium–thiolate family
作者： Kevin P Maresca , Frank J Femia , Grant H Bonavia , John W Babich , Jon Zubieta
DOI: 10.1016/S0020-1693(99)00290-X
关键词: Crystal structure 、 Substituent 、 Chemistry 、 Denticity 、 Crystallography 、 Cationic polymerization 、 Amine gas treating 、 Type (model theory) 、 Ligand
摘要: Abstract The ‘3+1’ concept of ligand addition to Group VII metaloxo species allows the facile preparation neutral complexes general type [MO(SXY)(SR)], where X=S, O, or N and Y=S O. However, if appropriate amine functionalities are incorporated into substituent R monodentate ligand, cationic oxometalate [MO(SXY)(SRNH x )] + may be routinely prepared. synthesis characterization a series this class reported. structures [ReO{(SCH 2 CH ) S}(C 5 H 4 NH-2-S)][Br], NH-4-S)][Br], S}(SCH NH 3 )][Cl], [ReO{C N-2-CH O-6-CH NH-2-S)}][Br] described compared other examples oxorhenium thiolate complexes.
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