Electrochemical properties of platinum and palladium electrodes in acetonitrile solutions
作者： O.A. Petrii , I.G. Khomchenko
DOI: 10.1016/S0022-0728(80)80174-4
关键词: Palladium 、 Perchlorate 、 Electrochemistry 、 Lithium perchlorate 、 Inorganic chemistry 、 Chemistry 、 Chemisorption 、 Platinum 、 Acetonitrile 、 Lithium
摘要: Abstract Differential capacity curves were plotted for renewed cross-sections of platinum and palladium electrodes under working solutions perchlorate lithium, sodium, tetraethylammonium tetraborate sodium in acetonitrile. In dilute lithium a minimum on the potential acetonitrile double electric layer at zero charge. The low values small dependence capcity permits assumption that strong chemisorption molecules solvent takes place surface metals. This conclusion is substantiated by comparison differences between potentials charge work function different Data obtained adsorption organic substances classes
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sci-hub.se 参考文章(13)
Roger Parsons, Elektrokhimiya : Vol. 1. Part 1, Academy of Sciences, U.S.S.R., Moscow, 1965, 14 roubles, 40 kopecks per annum Journal of Electroanalytical Chemistry. ,vol. 9, ,(1965) , 10.1016/0022-0728(65)85052-5
Jacques Vedel, Bernard Trémillon, Voltammétrie du système hydrogène-acide perchlorique dans l'acétonitrile, à une électrode de platine platiné Journal of Electroanalytical Chemistry (1959). ,vol. 1, pp. 241- 247 ,(1960) , 10.1016/0022-0728(60)85018-8
I N Rozhkov, Radical-cation Mechanism of the Anodic Fluorination of Organic Compounds Russian Chemical Reviews. ,vol. 45, pp. 615- 629 ,(1976) , 10.1070/RC1976V045N07ABEH002697
Roger Parsons, F.G.R. Zobel, The interphase between mercury and aqueous sodium dihydrogen phosphate Journal of Electroanalytical Chemistry. ,vol. 9, pp. 333- 348 ,(1965) , 10.1016/0022-0728(65)85029-X
Franco Magno, Gino Bontempelli, Electrochemical elimination of water in acetonitrile medium Journal of Electroanalytical Chemistry. ,vol. 39, pp. 489- 491 ,(1972) , 10.1016/S0022-0728(72)80173-6
Georges Valette, Antoinette Hamelin, Structure et propriétés de la couche double électrochimique à l'interphase argent/solutions aqueuses de fluorure de sodium Journal of Electroanalytical Chemistry. ,vol. 45, pp. 301- 319 ,(1973) , 10.1016/S0022-0728(73)80166-4
J. F. O'Donnell, J. T. Ayres, C. K. Mann, Preparation of High Purity Acetonitrile. Analytical Chemistry. ,vol. 37, pp. 1161- 1162 ,(1965) , 10.1021/AC60228A027
David C. Grahame, The Electrical Double Layer and the Theory of Electrocapillarity. Chemical Reviews. ,vol. 41, pp. 441- 501 ,(1947) , 10.1021/CR60130A002
P. Delahay, Ashok K. Vijh, Advances in Electrochemistry and Electrochemical Engineering Journal of The Electrochemical Society. ,vol. 117, ,(1964) , 10.1149/1.2407311
A. Frumkin, B. Damaskin, N. Grigoryev, I. Bagotskaya, Potentials of zero charge, interaction of metals with water and adsorption of organic substances—I. Potentials of zero charge and hydrophilicity of metals Electrochimica Acta. ,vol. 19, pp. 69- 74 ,(1974) , 10.1016/0013-4686(74)85058-9