Organometallic chemistry of fullerenes: ?2- and ?5-(?)complexes
作者： R. C. Haddon
DOI: 10.1002/(SICI)1096-987X(19980130)19:2<139::AID-JCC6>3.0.CO;2-V
关键词: Fullerene 、 Organometallic chemistry 、 Fullerene chemistry 、 Computational chemistry 、 Crystallography 、 Atom 、 Reactivity (chemistry) 、 Conjugated system 、 Metal 、 Carbon 、 Chemistry
摘要: The reactivity of the fullerenes is primarily a function their strain, as measured by pyramidalization angle or curvature conjugated carbon atoms. A consideration orientation π-orbitals shows that η2-complexation reactions lead to reaction products with are very similar those obtained from unstrained alkenes. Furthermore, large amount strain energy released in this reaction, so it clear just why important fullerene chemistry. On other hand, shown C60 poorly oriented for overlap an exohedral metal atom centered over five- six-membered rings, but well disposed endohedral under rings. © 1998 John Wiley & Sons, Inc. J Comput Chem 19: 139–143,
sci-hub.se 参考文章(21)
Masaya Sawamura, Hitoshi Iikura, Eiichi Nakamura, THE FIRST PENTAHAPTOFULLERENE METAL COMPLEXES Journal of the American Chemical Society. ,vol. 118, pp. 12850- 12851 ,(1996) , 10.1021/JA962681X
R. C. Haddon, C60: Sphere or Polyhedron? Journal of the American Chemical Society. ,vol. 119, pp. 1797- 1798 ,(1997) , 10.1021/JA9637659
Alan L. Balch, Vincent J. Catalano, Joong W. Lee, Accumulating evidence for the selective reactivity of the 6-6 ring fusion of fullerene, C60. Preparation and structure of (.eta.2-C60)Ir(CO)Cl(PPh3)2.cntdot.5C6H6 Inorganic Chemistry. ,vol. 30, pp. 3980- 3981 ,(1991) , 10.1021/IC00021A003
Andreas Hirsch, The chemistry of the fullerenes ,(1994)
Dirk Bakowies, Walter Thiel, MNDO Study of Large Carbon Clusters Journal of the American Chemical Society. ,vol. 113, pp. 3704- 3714 ,(1991) , 10.1021/JA00010A012
Alan L. Balch, Vincent J. Catalano, Joong W. Lee, Marilyn M. Olmstead, Sean R. Parkin, (.eta.2-C70)Ir(CO)Cl(PPh3)2: the synthesis and structure of an iridium organometallic derivative of a higher fullerene Journal of the American Chemical Society. ,vol. 113, pp. 8953- 8955 ,(1991) , 10.1021/JA00023A057
R. C. Haddon, Chemistry of the fullerenes: the manifestation of strain in a class of continuous aromatic molecules. Science. ,vol. 261, pp. 1545- 1550 ,(1993) , 10.1126/SCIENCE.261.5128.1545
Robert C. Haddon, Rehybridization and .pi.-orbital overlap in nonplanar conjugated organic molecules: .pi.-orbital axis vector (POAV) analysis and three-dimensional Hueckel molecular orbital (3D-HMO) theory Journal of the American Chemical Society. ,vol. 109, pp. 1676- 1685 ,(1987) , 10.1021/JA00240A013
T. G. Schmalz, W. A. Seitz, D. J. Klein, G. E. Hite, Elemental carbon cages Journal of the American Chemical Society. ,vol. 110, pp. 1113- 1127 ,(1988) , 10.1021/JA00212A020
T. Jon Seiders, Kim K. Baldridge, Joseph M. O'Connor, Jay S. Siegel, Hexahapto Metal Coordination to Curved Polyaromatic Hydrocarbon Surfaces: The First Transition Metal Corannulene Complex Journal of the American Chemical Society. ,vol. 119, pp. 4781- 4782 ,(1997) , 10.1021/JA964380T