(Pentamethylcyclopentadienyl)cobalt(III)-Catalyzed C-H Bond Functionalization: From Discovery to Unique Reactivity and Selectivity

作者: Tatsuhiko Yoshino , Shigeki Matsunaga

DOI: 10.1002/ADSC.201700042

关键词: RhodiumCatalysisMedicinal chemistrySelectivityReactivity (chemistry)Surface modificationChemistryIonic radiusOrganic chemistryCobaltElectronegativity

摘要: … We focus on such differences and the unique reactivity of the Cp*Co(III) catalysts after … would have a relatively large atomic charge on the cobalt center, and the ionic radius of …

参考文章(220)
Yang Li, Bi-Jie Li, Wen-Hua Wang, Wei-Ping Huang, Xi-Sha Zhang, Kang Chen, Zhang-Jie Shi, Rhodium‐Catalyzed Direct Addition of Aryl CH Bonds to N‐Sulfonyl Aldimines Angewandte Chemie. ,vol. 50, pp. 2115- 2119 ,(2011) , 10.1002/ANIE.201007464
Malay Sen, Deepti Kalsi, Basker Sundararaju, Cobalt(III)‐Catalyzed Dehydrative [4+2] Annulation of Oxime with Alkyne by C ? H and N ? OH Activation Chemistry: A European Journal. ,vol. 21, pp. 15529- 15533 ,(2015) , 10.1002/CHEM.201503643
Junichiro Yamaguchi, Atsushi D. Yamaguchi, Kenichiro Itami, Funktionalisierung von C-H-Bindungen: neue Synthesemethoden für Naturstoffe und Pharmazeutika Angewandte Chemie. ,vol. 124, pp. 9092- 9142 ,(2012) , 10.1002/ANGE.201201666
Frederic W. Patureau, Frank Glorius, Oxidierende dirigierende Gruppen ermöglichen effiziente und innovative C‐H‐Aktivierungsreaktionen Angewandte Chemie. ,vol. 123, pp. 2021- 2023 ,(2011) , 10.1002/ANGE.201007241
Dongbing Zhao, Ju Hyun Kim, Linda Stegemann, Cristian A. Strassert, Frank Glorius, Cobalt(III)‐Catalyzed Directed C ? H Coupling with Diazo Compounds: Straightforward Access towards Extended π‐Systems Angewandte Chemie. ,vol. 54, pp. 4508- 4511 ,(2015) , 10.1002/ANIE.201411994
Junichiro Yamaguchi, Kei Muto, Kenichiro Itami, Recent Progress in Nickel-Catalyzed Biaryl Coupling European Journal of Organic Chemistry. ,vol. 2013, pp. 19- 30 ,(2013) , 10.1002/EJOC.201200914