作者: Rida Tajau , Rosiah Rohani , Mek Zah Salleh
DOI: 10.1007/S10924-020-01797-6
关键词: Fourier transform infrared spectroscopy 、 Yield (chemistry) 、 Acrylic acid 、 Chemical engineering 、 Proton NMR 、 Materials science 、 Crystallization 、 Polymer 、 Crystallinity 、 Biopolymer
摘要: The utilisation of palm oil-based polymers as biomaterials has received considerable interest to support further expansion in the biomedical field they pose potential capability competing with synthetic per their physicochemical, thermal, and crystallinity properties. In this study, synthesis a new green biopolymer, namely acrylated olein (APO) from precursor, was developed. APO synthesised via ring-opening process epoxidised (EPOo) acrylic acid triethylamine. acrylation produced an high yield (86.64%) molecular weight 1750 Da. ester group representing confirmed through proton nuclear magnetic resonance (1H-NMR), carbon-13 (13C-NMR) Fourier transform infrared (FTIR), which revealed promising biodegradable point structure. Meanwhile, thermal crystallisation profiles showed single-stage decomposition pattern its triglycerides (TAGs) crystal formation melting behaviour. As result, desired polymer obtained, possessed chemical functional group, amorphous, low