Combined elemental analysis of ancient glass beads by means of ion beam, portable XRF, and EPMA techniques

作者: D. Sokaras , A. G. Karydas , A. Oikonomou , N. Zacharias , K. Beltsios

DOI: 10.1007/S00216-009-3156-3

关键词: MetallurgyElectron microprobeIon beam analysisElemental analysisChemistryMineralogyIon beamBeadCharacterization (materials science)Spectrometer

摘要: Ion beam analysis (IBA)- and X-ray fluorescence (XRF)-based techniques have been well adopted in cultural-heritage-related analytical studies covering a wide range of diagnostic role, i.e., from screening purposes up to full quantitative characterization. In this work, systematic research was carried out towards the identification evaluation advantages limitations laboratory-based (IBA, electron probe microanalyzer) portable (milli-XRF micro-XRF) techniques. The study focused on an Archaic glass bead collection recently excavated city Thebes (mainland, Greece), order suggest optimized synergistic methodology for similar assess reliability quantification procedure analyses conducted particular by XRF spectrometers. All employed methodologies proved efficient provide consistent way characterization composition, with sensitivity depending technique. obtained compositional data solid basis understanding main technological features related raw major minor materials utilized manufacture Thebian ancient collection.

参考文章(40)
T Rehren, P Triantafyllidis, L Spencer, The primary production of glass at Hellenistic Rhodes In: Cool, H, (ed.) Annales du 16e Congres de l'Association Internationale pour l'Histoire du Verre. (pp. 39-43). : Nottingham. (2005). ,(2005)
E. Rimini, James W. Mayer, J. W. Mayer, Ion Beam Handbook for Material Analysis ,(1978)
J. Zarzycki, Glasses and the vitreous state ,(1991)
Alex von Bohlen, Stefan Röhrs, Joseph Salomon, Spatially resolved element analysis of historical violin varnishes by use of μPIXE Analytical and Bioanalytical Chemistry. ,vol. 387, pp. 781- 790 ,(2007) , 10.1007/S00216-006-0777-7
N. Zacharias, K. Beltsios, A. Oikonomou, A.G. Karydas, Y. Bassiakos, C.T. Michael, Ch. Zarkadas, Solid-state luminescence for the optical examination of archaeological glass beads Optical Materials. ,vol. 30, pp. 1127- 1133 ,(2008) , 10.1016/J.OPTMAT.2007.05.036
Marek Trojanowicz, Modern chemical analysis in archaeometry. Analytical and Bioanalytical Chemistry. ,vol. 391, pp. 915- 918 ,(2008) , 10.1007/S00216-008-2077-X
Ž. Šmit, K. Janssens, E. Bulska, B. Wagner, M. Kos, I. Lazar, Trace element fingerprinting of façon-de-Venise glass Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 239, pp. 94- 99 ,(2005) , 10.1016/J.NIMB.2005.06.182
Dimosthenis Sokaras, Andreas-Germanos Karydas, Wolfgang Malzer, Roman Schütz, Birgit Kanngießer, Nataša Grlj, Primož Pelicon, Matjaz Žitnik, None, Quantitative analysis in confocal micro-PIXE—general concept and layered materials Journal of Analytical Atomic Spectrometry. ,vol. 24, pp. 611- 621 ,(2009) , 10.1039/B817100A
Philippe Colomban, Marie-Pierre Etcheverry, Magali Asquier, Mathieu Bounichou, Aurélie Tournié, Raman identification of ancient stained glasses and their degree of deterioration Journal of Raman Spectroscopy. ,vol. 37, pp. 614- 626 ,(2006) , 10.1002/JRS.1495