Method of producing tetrakis(pentafluorophenyl)borate derivatives using pentafluorophenylmagnesium derivatives.

作者: Eiichi Kaji , Takeo Yamane , Kenji Ishimaru , Yoshihiko Ikeda

DOI:

关键词: HalogenBoronChemistryAtom (order theory)Medicinal chemistryInorganic chemistry

摘要: A method of producing tetrakis(pentafluorophenyl)borate derivatives the formula [(C 6 F 5 ) 4 B] 2-n MgX n wherein denotes an integer 0 or 1 and X a halogen atom, using pentafluorophenylmagnesium (C , as source pentafluorophenyl group.

参考文章(3)
Paul Raff, Georg Wittig, Process of producing sodium tetraphenylboron ,(1954)
J. L. W. Pohlmann, F. E. Brinckmann, Preparation and Characterization of Group III A Derivatives Zeitschrift für Naturforschung B. ,vol. 20, pp. 5- 11 ,(1965) , 10.1515/ZNB-1965-0102
A.G. Massey, A.J. Park, Perfluorophenyl derivatives of the elements Journal of Organometallic Chemistry. ,vol. 5, pp. 218- 225 ,(1966) , 10.1016/S0022-328X(00)80358-7