Ionic conductivity of a PMMA based gel polymer electrolyte and its performance in solid state electrochemical cells

作者: Y.M.C.D. Jayathilake , K.S. Perera , K.P. Vidanapathirana , L.R.A.K. Bandara

DOI: 10.4038/SLJP.V15I0.6638

关键词: ElectrochemistryElectrochemical cellLithiumElectrolytePropylene carbonateIonic conductivityConductivityEthylene carbonateChemical engineering

摘要: Gel polymer electrolytes are known to be very suitable for many electrochemical devices. They Gel They have been extensively studied lithium based cells. But, due several drawbacks of cells such as safety issues, handling problems and toxicity, it is the time develop non Li In this study, ionic conductivity a gel electrolyte (GPE) on polymethylmethacrylate, ethylene carbonate, propylene carbonate tetrapropylammonium iodide its performance in an Mg / C: I 2 cell was investigated. GPE prepared by varying salt concentration using hot pressed method composition, 20 PMMA 30 EC PC 40 Pr 4 N + showed highest 5.02 x 10 -3 Scm -1 at 28 ° C. The form C+I average open circuit voltage 1.9 V. short current 3.3 mA. It possible observe good stability self discharge characteristics cell. DOI: http://dx.doi.org/10.4038/sljp.v15i0.6638 Sri Lankan Journal Physics, Vol. 15 (2014) 11-17

参考文章(10)
Izumi Yamada, Yasutoshi Iriyama, Takeshi Abe, Zempachi Ogumi, Lithium-ion transfer between LixCoO2 and polymer gel electrolytes Science and Technology of Advanced Materials. ,vol. 7, pp. 519- 523 ,(2006) , 10.1016/J.STAM.2006.07.005
R.L. Lavall, S. Ferrari, C. Tomasi, M. Marzantowicz, E. Quartarone, M. Fagnoni, P. Mustarelli, M.L. Saladino, MCM-41 silica effect on gel polymer electrolytes based on thermoplastic polyurethane Electrochimica Acta. ,vol. 60, pp. 359- 365 ,(2012) , 10.1016/J.ELECTACTA.2011.11.073
Zhang Lan, Jihuai Wu, Dongbo Wang, Sancun Hao, Jianming Lin, Yunfang Huang, Quasi-solid state dye-sensitized solar cells based on gel polymer electrolyte with poly(acrylonitrile-co-styrene)/NaI+I2 Solar Energy. ,vol. 80, pp. 1483- 1488 ,(2006) , 10.1016/J.SOLENER.2005.11.007
TMWJ Bandara, T Svensson, MAKL Dissanayake, M Furlani, WJMJSR Jayasundara, PSL Fernando, I Albinsson, BE Mellander, Conductivity behaviour in novel quasi-solid-state electrolyte based on polyacrylonitrile and tetrahexylammonium iodide intended for dye sensitized solar cells Journal of The National Science Foundation of Sri Lanka. ,vol. 41, pp. 175- 184 ,(2013) , 10.4038/JNSFSR.V41I3.6056
Hongxun Yang, Miaoliang Huang, Jihuai Wu, Zhang Lan, Sancun Hao, Jianming Lin, The polymer gel electrolyte based on poly(methyl methacrylate) and its application in quasi-solid-state dye-sensitized solar cells Materials Chemistry and Physics. ,vol. 110, pp. 38- 42 ,(2008) , 10.1016/J.MATCHEMPHYS.2008.01.010
Deepak Kumar, S.A. Hashmi, Ionic liquid based sodium ion conducting gel polymer electrolytes Solid State Ionics. ,vol. 181, pp. 416- 423 ,(2010) , 10.1016/J.SSI.2010.01.025
Soo-Kyeong Jeong, Yun-Kyung Jo, Nam-Ju Jo, Decoupled ion conduction mechanism of poly(vinyl alcohol) based Mg-conducting solid polymer electrolyte Electrochimica Acta. ,vol. 52, pp. 1549- 1555 ,(2006) , 10.1016/J.ELECTACTA.2006.02.061
M. A. K. L. Dissanayake, C. A. Thotawatthage, G. K. R. Senadeera, T. M. W. J. Bandara, W. J. M. J. S. R. Jayasundara, B.-E. Mellander, Efficiency enhancement in dye sensitized solar cells based on PAN gel electrolyte with Pr4NI + MgI2 binary iodide salt mixture Journal of Applied Electrochemistry. ,vol. 43, pp. 891- 901 ,(2013) , 10.1007/S10800-013-0582-X
Anji Reddy Polu, Ranveer Kumar, K Vijaya Kumar, Ionic conductivity and electrochemical cell studies of new Mg 2+ ion conducting PVA/PEG based polymer blend electrolytes Advanced Materials Letters. ,vol. 3, pp. 406- 409 ,(2012) , 10.5185/AMLETT.2012.6375