Crystal Structures of Au2 Complex and Au25 Nanocluster and Mechanistic Insight into the Conversion of Polydisperse Nanoparticles into Monodisperse Au25 Nanoclusters

作者: Huifeng Qian , William T. Eckenhoff , Mark E. Bier , Tomislav Pintauer , Rongchao Jin

DOI: 10.1021/IC2012292

关键词: ChemistryDispersityPhosphineElectrospray ionizationCrystallographyCounterionCrystal structureNanoclustersNanoparticleCluster (physics)

摘要: … The optical spectrum of the [Au 2 (PPh 3 ) 2 (SC 2 … spectra and ESI mass spectra during the thiol etching process (Figure 5). The evolution of the UV–vis spectra (Figure 5A) indicates the …

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