Products of carbothermic reduction of Fe–Cr–O and Fe–Cr–Ni–O systems

作者: Yan-ling ZHANG , Yang LIU , Wen-jie WEI

DOI: 10.1016/S1003-6326(14)63181-2

关键词: Materials scienceReduction (complexity)Molar ratioScanning electron microscopeNon-blocking I/OMicrostructureMetallurgyEnergy Dispersive SpectrometerAnalytical chemistryResidual carbonDiffraction

摘要: Abstract The reduction behaviors and characteristics of products the Fe–Cr–O system (FeCr 2 O 4 Fe 3 +Cr ) Fe–Cr–Ni–O (Fe +NiO) under various conditions were studied. results show that more Fe-Cr or Fe-Cr-Ni solution less residual carbon content obtained at higher temperatures lower initial molar ratio C to ( n : ). degree was highly dependent on both time temperature, greatly increased with increasing each temperature. generated during carbothermic examined using X-ray diffraction (XRD). A scanning electron microscope (SEM) coupled energy dispersive spectrometer used observe microstructure distribution elements in phases final Fe–Cr–Ni–O.

参考文章(18)
AK Lahiri, M Gornerup, Reduction of electric arc furnace slags in stainless steelmaking - Part 2 Mechanism of CrOx reduction Ironmaking & Steelmaking. ,vol. 25, pp. 382- 386 ,(1998)
Dolly Chakraborty, S. Ranganathan, S. N. Sinha, Investigations on the carbothermic reduction of chromite ores Metallurgical and Materials Transactions B-process Metallurgy and Materials Processing Science. ,vol. 36, pp. 437- 444 ,(2005) , 10.1007/S11663-005-0034-Z
Zhang Huaiwei, Hong Xin, An overview for the utilization of wastes from stainless steel industries Resources Conservation and Recycling. ,vol. 55, pp. 745- 754 ,(2011) , 10.1016/J.RESCONREC.2011.03.005
Mo-tang TANG, Ji PENG, Bing PENG, Di YU, Chao-bo TANG, Thermal solidification of stainless steelmaking dust Transactions of Nonferrous Metals Society of China. ,vol. 18, pp. 202- 206 ,(2008) , 10.1016/S1003-6326(08)60036-9
Cyro Takano, Adolfo Pillihuaman Zambrano, Alberto Eloy Anduze Nogueira, Marcelo Breda Mourao, Yoshiaki Iguchi, Chromites Reduction Reaction Mechanisms in Carbon–Chromites Composite Agglomerates at 1773 K Isij International. ,vol. 47, pp. 1585- 1589 ,(2007) , 10.2355/ISIJINTERNATIONAL.47.1585
Noboru Yoshikawa, Ken-ichi Mashiko, You Sasaki, Shoji Taniguchi, Hidekazu Todoroki, Microwave Carbo-thermal Reduction for Recycling of Cr from Cr-containing Steel Making Wastes Isij International. ,vol. 48, pp. 690- 695 ,(2008) , 10.2355/ISIJINTERNATIONAL.48.690
Ping Ma, Bo Lindblom, Bo Bjorkman, Mechanism study on solid‐state reduction in the Fe2O3–NiO–Cr2O3–C system using thermal analyses Scandinavian Journal of Metallurgy. ,vol. 34, pp. 22- 30 ,(2005) , 10.1111/J.1600-0692.2005.00715.X
Tomoyuki Mori, Jian Yang, Mamoru Kuwabara, Mechanism of Carbothermic Reduction of Chromium Oxide Isij International. ,vol. 47, pp. 1387- 1393 ,(2007) , 10.2355/ISIJINTERNATIONAL.47.1387
K.S. Abdel-Halim, M.H. Khedr, M.I. Nasr, M.Sh. Abdel-wahab, Carbothermic reduction kinetics of nanocrystallite Fe2O3/NiO composites for the production of Fe/Ni alloy Journal of Alloys and Compounds. ,vol. 463, pp. 585- 590 ,(2008) , 10.1016/J.JALLCOM.2008.02.026