作者: E. Tomaszewicz , S.M. Kaczmarek , H. Fuks
DOI: 10.1016/J.MATCHEMPHYS.2010.03.052
关键词: Electron paramagnetic resonance 、 Cadmium 、 Rare earth 、 Scheelite 、 Inorganic chemistry 、 Solubility 、 Annealing (metallurgy) 、 Metal 、 Electron resonance 、 Chemistry
摘要: Abstract New cadmium and rare-earth metal molybdates with the formula Cd0.25RE0.50MoO4 (RE = Pr, Nd, Sm–Dy) were synthesized by solid-state reaction of CdMoO4 corresponding RE2(MoO4)3. The obtained compounds crystallize in scheelite-type structure. They characterized here XRD, DTA-TG, IR EPR methods. showed solubility forming CdxRE2−2x(MoO4)3−2x (0.50