Relationship among Redox Potentials, Proton Dissociation Constants of Pyrrolic Nitrogens, and in Vivo and in Vitro Superoxide Dismutating Activities of Manganese(III) and Iron(III) Water-Soluble Porphyrins

作者: Ines Batinić-Haberle , Ivan Spasojević , Peter Hambright , Ludmil Benov , Alvin L. Crumbliss

DOI: 10.1021/IC990118K

关键词: SuperoxideInorganic chemistryNitrogenIn vivoRedoxAcid dissociation constantManganeseChemistryReaction rate constantEnzyme kinetics

摘要: … and for treating pathologies in which the superoxide radical and its progeny are suspected of … The advantages of the ortho compound are due to a higher metal-centered redox potential, …

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