Electrospinning fabrication and luminescent properties of SrMoO4:Sm3+ nanofibers

作者: Pingfan Du , Lixin Song , Jie Xiong , Houbao Cao , Zhenqiang Xi

DOI: 10.1016/J.JALLCOM.2012.06.025

关键词: PhotoluminescenceNanotechnologySamariumElectrospinningTetragonal crystal systemNanofiberMolybdateLuminescenceMaterials scienceAnalytical chemistryDoping

摘要: Abstract Samarium ions doped strontium molybdate (SrMoO 4 :Sm 3+ ) nanofibers (NFs) were fabricated by a simple electrospinning process. The obtained SrMoO NFs are composed of scheelite-type tetragonal phase, and the have an average diameter ca. 90 nm. Under 275 nm ultraviolet (UV) excitation, show orange-red fluorescent property symbolized characteristic emission (606 nm) resulting from G 5/2  →  6 H 7/2 energy level transition Sm . And photoluminescence (PL) emissi on intensity is superior to that nanoparticles (NPs) counterpart under same doping concentrations. effect concentrations was also investigated. result reveals concentration quenching will occur when content exceeds 2 at.%. In other words, optimal luminescent performance such concentration.

参考文章(57)
Xiaoming Liu, Liushui Yan, Jianping Zou, Tunable Cathodoluminescence Properties of Tb3 + -Doped La2O3 Nanocrystalline Phosphors Journal of The Electrochemical Society. ,vol. 157, pp. 1- ,(2010) , 10.1149/1.3262007
Xu Li, Li Guan, Mingsheng Sun, Haiyan Liu, Zhiping Yang, Qinglin Guo, Guangsheng Fu, Luminescent properties of Dy3+ doped SrMoO4 phosphor Journal of Luminescence. ,vol. 131, pp. 1022- 1025 ,(2011) , 10.1016/J.JLUMIN.2011.01.015
D. L. Dexter, James H. Schulman, Theory of Concentration Quenching in Inorganic Phosphors The Journal of Chemical Physics. ,vol. 22, pp. 1063- 1070 ,(1954) , 10.1063/1.1740265
Yuanming Zhang, Fada Yang, Jun Yang, Yu Tang, Peng Yuan, Synthesis of crystalline SrMoO4 nanowires from polyoxometalates Solid State Communications. ,vol. 133, pp. 759- 763 ,(2005) , 10.1016/J.SSC.2005.01.016
Piaoping Yang, Chunxia Li, Wenxin Wang, Zewei Quan, Shili Gai, Jun Lin, None, Uniform AMoO4:Ln (A=Sr2+, Ba2+; Ln=Eu3+, Tb3+) submicron particles: Solvothermal synthesis and luminescent properties Journal of Solid State Chemistry. ,vol. 182, pp. 2510- 2520 ,(2009) , 10.1016/J.JSSC.2009.07.009
Yeqing Chen, Hyun Kyoung Yang, Sung Wook Park, Byung Kee Moon, Byung Chun Choi, Jung Hyun Jeong, Kwang Ho Kim, Characterization and photoluminescent enhancement of Li+ corporation effect on CaWO4:Eu3+ phosphor Journal of Alloys and Compounds. ,vol. 511, pp. 123- 128 ,(2012) , 10.1016/J.JALLCOM.2011.09.004
Ye Jin, Jiahua Zhang, Shaozhe Lü, Haifeng Zhao, Xia Zhang, Xiao-jun Wang, Fabrication of Eu3+ and Sm3+ Codoped Micro/Nanosized MMoO4 (M = Ca, Ba, and Sr) via Facile Hydrothermal Method and Their Photoluminescence Properties through Energy Transfer Journal of Physical Chemistry C. ,vol. 112, pp. 5860- 5864 ,(2008) , 10.1021/JP800559F
Rodrigo M. Petoral, Fredrik Söderlind, Anna Klasson, Anke Suska, Marc A. Fortin, Natalia Abrikossova, Linnéa Selegård, Per-Olov Käll, Maria Engström, Kajsa Uvdal, Synthesis and Characterization of Tb3+-Doped Gd2O3 Nanocrystals : A Bifunctional Material with Combined Fluorescent Labeling and MRI Contrast Agent Properties Journal of Physical Chemistry C. ,vol. 113, pp. 6913- 6920 ,(2009) , 10.1021/JP808708M
Jian Bi, Chun-Hua Cui, Xin Lai, Fang Shi, Dao-Jiang Gao, Synthesis of luminescent SrMoO4 thin films by a non-reversible galvanic cell method Materials Research Bulletin. ,vol. 43, pp. 743- 747 ,(2008) , 10.1016/J.MATERRESBULL.2007.03.021
Lianping Chen, Yuanhong Gao, Mechanisms and applications of cell electrochemical technique to prepare luminescent SrMoO4 thin films Chemical Engineering Journal. ,vol. 131, pp. 181- 185 ,(2007) , 10.1016/J.CEJ.2006.12.034