Interchromophore orientation scaffolding by m-terphenyl oxacyclophanes
作者： Anshuman Mangalum , Brad P. Morgan , Jessica M. Hanley , Kristine M. Jecen , Charles J. McGill
DOI: 10.1039/C0CC00247J
关键词: Terphenyl 、 Materials science 、 Orientation (graph theory) 、 Crystallography 、 Scaffold
摘要: … Developing rational design principles for organic electronics thus requires a deeper understanding of inter-π-system interactions, spurring a multitude of theoretical 19–22 and experimental studies focused on scaffolded inter-π-system geometries. In this vein, we have designed a modular scaffold capable of replicating multiple types of inter-π-system orientations through the assembly of common building blocks. … Because the relative orientation of the upper and lower π-systems dictates the interchromophore interaction, we believed that …
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